Structural, physical, and chemical properties of fluorous compounds.
作者： John A. Gladysz , Markus Jurisch
DOI: 10.1007/128_2011_282
关键词:
摘要: The sizes and structures of fluorous molecules are analyzed, particularly with respect to the helical conformations perfluoroalkyl segments their phase separation in crystal lattices. Basic molecular properties, bond energies, special bonding motifs reviewed. Solubility, adsorption, related phenomena treated. Miscibilities solvents, partition coefficients solutes fluorous/organic biphase mixtures, analyzed. Electronic effects NMR properties discussed, some reactions involving fluorinated parts substances presented.
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Bradley M. Berven, George A. Koutsantonis, Brian W. Skelton, Robert D. Trengove, Allan H. White, Highly Fluorous Complexes of Ruthenium and Osmium and Their Solubility in Supercritical Carbon Dioxide Inorganic Chemistry. ,vol. 48, pp. 11832- 11842 ,(2009) , 10.1021/IC901880F
Michiel C. A. van Vliet, Isabel W. C. E. Arends, Roger A. Sheldon, Perfluoroheptadecan-9-one: a selective and reusable catalyst for epoxidations with hydrogen peroxide Chemical Communications. pp. 263- 264 ,(1999) , 10.1039/A809204D
Joep van den Broeke, Ferry Winter, Berth-Jan Deelman, Gerard van Koten, A highly fluorous room-temperature ionic liquid exhibiting fluorous biphasic behavior and its use in catalyst recycling. Organic Letters. ,vol. 4, pp. 3851- 3854 ,(2002) , 10.1021/OL026700L
Tsuyoshi Miura, Kosuke Nakashima, Norihiro Tada, Akichika Itoh, An effective and catalytic oxidation using recyclable fluorous IBX. Chemical Communications. ,vol. 47, pp. 1875- 1877 ,(2011) , 10.1039/C0CC03149F
Jack D. Dunitz, Organic Fluorine: Odd Man Out ChemBioChem. ,vol. 5, pp. 614- 621 ,(2004) , 10.1002/CBIC.200300801
Kristi L. O’Neal, Stephen G. Weber, Molecular and Ionic Hydrogen Bond Formation in Fluorous Solvents Journal of Physical Chemistry B. ,vol. 113, pp. 149- 158 ,(2009) , 10.1021/JP8084155
Seung Soon Jang, Mario Blanco, William A. Goddard, Gregg Caldwell, Richard B. Ross, The Source of Helicity in Perfluorinated N-Alkanes Macromolecules. ,vol. 36, pp. 5331- 5341 ,(2003) , 10.1021/MA025645T
Mara G Freire, Lígia Gomes, Luís MNBF Santos, Isabel M Marrucho, Joao AP Coutinho, None, Water solubility in linear fluoroalkanes used in blood substitute formulations. Journal of Physical Chemistry B. ,vol. 110, pp. 22923- 22929 ,(2006) , 10.1021/JP0622942
Peer Kirsch, Matthias Bremer, Understanding Fluorine Effects in Liquid Crystals ChemPhysChem. ,vol. 11, pp. 357- 360 ,(2010) , 10.1002/CPHC.200900745
Daniela Vuluga, Julien Legros, Benoit Crousse, Danièle Bonnet-Delpon, Fluorous 4-N,N-dimethylaminopyridine (DMAP) salts as simple recyclable acylation catalysts. Chemistry: A European Journal. ,vol. 16, pp. 1776- 1779 ,(2010) , 10.1002/CHEM.200902982