Process for stereoselectively hydrolyzing, transesterifying or esterifying with immobilized isozyme of lipase from candida rugosa
作者： Carrington S. Cobbs , Adrien P. Malick , Gary J. Calton , Animesh Goswami , John P. Hamman
DOI:
关键词:
摘要: An immobilized isozyme of Lipase MY or AY from Candida rugosa is used for stereoselectively hydrolyzing racemic mixtures esters 2-substituted acids, other than 2-halo propionic transesterifying acids esterify alcohols, at high enantiomeric excess, in an organic solvent. Immobilization the may be carried out presence acid such as stearic acid. The with a fatty ester that increases stereoselectivity rate hydrolysis mixture esters.
google.com.tr参考文章(26)
Alan E. Walts, Ellen M. Fox, Resolution of glycidyl esters to high enantiomeric excess ,(1988)
Takaharu Matsuo, Norio Sawamura, Kazunobu Tsumura, Yoshitaka Ebihara, Process for preparing enzyme preparation ,(1987)
Peter Eigtved, Immobilized Mucor miehe lipase for transesterification ,(1987)
Takaharu Matsuo, Norio Sawamura, Wataru Hashida, Yukio Hashimoto, Method for enzymatic transesterification of lipid and enzyme used therein ,(1981)
Frank J. Smith, Jerry M. Roper, (S) α-(cyano-3-phenoxy-benzyl acetate ,(1985)
Nabil A. Elshourbagy, C.F. Wilkinson, The role of DNA-dependent RNA polymerases in microsomal enzyme induction in southern armyworm (Spodoptera eridania) larvae Insect Biochemistry. ,vol. 8, pp. 425- 433 ,(1978) , 10.1016/0020-1790(78)90055-0
Samun K. Dahod, Patricia Siuta-Mangano, Carbon tetrachloride-promoted stereo selective hydrolysis of methyl-2-chloropropionate by lipase. Biotechnology and Bioengineering. ,vol. 30, pp. 995- 999 ,(1987) , 10.1002/BIT.260300813
Richard S. Schifreen, Peter W. Carr, An investigation of the kinetic characteristics of the lipase from candida cylindracea for its potential in triglyceride analysis Analytical Letters. ,vol. 12, pp. 47- 69 ,(1979) , 10.1080/00032717908082518
G. Benzonana, S. Esposito, On the positional and chain specificities of Candida cylindracea lipase Biochimica et Biophysica Acta (BBA) - Lipids and Lipid Metabolism. ,vol. 231, pp. 15- 22 ,(1971) , 10.1016/0005-2760(71)90251-7
John Caldwell, Andrew J. Hutt, Sylvie Fournel-Gigleux, The metabolic chiral inversion and dispositional enantioselectivity of the 2-arylpropionic acids and their biological consequences Biochemical Pharmacology. ,vol. 37, pp. 105- 114 ,(1988) , 10.1016/0006-2952(88)90762-9