Direct incorporation of carbon dioxide in poly(glycidyl methacrylate) and its application to the synthesis of hydrogel
作者： Dae-Won Park , Kyung-Hoon Kim , Sung-Young Park , Chung-Ki Sung , Sang-Wook Park
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摘要: This study is related to an integrated process for the application of CO2 poly(hydroxy urethane) and hydrogel viapoly(1,3-dioxolane-2-oxo-4-yl)methyl methacrylate [poly (DOMA)]. Quaternary ammonium salts showed good catalytic activity in synthesis poly(DOMA) by direct incorporation into poly(glycidyl methacrylate) [poly(GMA)]. Poly[3-(N-butylcarbamoyloxy)-2-hydroxypropyl methacrylate] [poly(CHPMA)] was successfully synthesized from n-butylamine. Hydrogels were also prepared poly(CHPMA), using several diisocyanates as crosslinkers, their swelling degrees studied measuring water content hydrogels.
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sci-hub.se 参考文章(11)
Handbook of phase transfer catalysis Blackie Academic & Professional. ,(1997) , 10.1007/978-94-009-0023-3
Marc Halpern, Phase-Transfer Catalysis Ullmann's Encyclopedia of Industrial Chemistry. ,(1994) , 10.1002/14356007.A19_293
Nobuhiro Kihara, Takeshi Endo, Synthesis and reaction of polymethacrylate bearing cyclic carbonate moieties in the side chain Macromolecular Chemistry and Physics. ,vol. 193, pp. 1481- 1492 ,(1992) , 10.1002/MACP.1992.021930624
Nobuhiro Kihara, Takeshi Endo, Synthesis and properties of poly(hydroxyurethane)s Journal of Polymer Science Part A. ,vol. 31, pp. 2765- 2773 ,(1993) , 10.1002/POLA.1993.080311113
W. J. Peppel, Preparation and Properties of the Alkylene Carbonates Industrial & Engineering Chemistry. ,vol. 50, pp. 767- 770 ,(1958) , 10.1021/IE50581A030
Nobuhiro Kihara, Takeshi Endo, Incorporation of carbon dioxide into poly(glycidyl methacrylate) Macromolecules. ,vol. 25, pp. 4824- 4825 ,(1992) , 10.1021/MA00044A053
Katsuto Otake, Hiroshi Inomata, Mikio Konno, Shozaburo Saito, Thermal analysis of the volume phase transition with N-isopropylacrylamide gels Macromolecules. ,vol. 23, pp. 283- 289 ,(1990) , 10.1021/MA00203A049
Nobuhiro Kihara, Nobutaka Hara, Takeshi Endo, Catalytic activity of various salts in the reaction of 2,3-epoxypropyl phenyl ether and carbon dioxide under atmospheric pressure Journal of Organic Chemistry. ,vol. 58, pp. 6198- 6202 ,(1993) , 10.1021/JO00075A011
Tae Gwan Park, Allan S. Hoffman, Synthesis and characterization of pH- and/or temperature-sensitive hydrogels Journal of Applied Polymer Science. ,vol. 46, pp. 659- 671 ,(1992) , 10.1002/APP.1992.070460413
J. Y. Moon, J. G. Yang, S. M. Jung, D. W. Park, J. K. Lee, A kinetic study on the reaction between glycidyl vinyl ether and carbon dioxide with quaternary ammonium salts as catalyst Reaction Kinetics and Catalysis Letters. ,vol. 61, pp. 315- 322 ,(1997) , 10.1007/BF02478388