High-Density Sodium and Lithium Ion Battery Anodes from Banana Peels

作者: Elmira Memarzadeh Lotfabad , Jia Ding , Kai Cui , Alireza Kohandehghan , W. Peter Kalisvaart

DOI: 10.1021/NN502045Y

关键词:

摘要: Banana peel pseudographite (BPPG) offers superb dual functionality for sodium ion battery (NIB) and lithium (LIB) anodes. The materials possess low surface areas (19–217 m2 g–1) a relatively high electrode packing density (0.75 g cm–3 vs ∼1 graphite). Tested against Na, BPPG delivers gravimetric (and volumetric) capacity of 355 mAh g–1 (by active material ∼700 cm–3, by volume ∼270 cm–3) after 10 cycles at 50 mA g–1. A nearly flat ∼200 plateau that is below 0.1 V minimal charge/discharge voltage hysteresis make direct electrochemical analogue to graphite but with Na. charge 221 500 degraded 7% 600 cycles, while 336 100 mAg–1 11% 300 in both cases ∼100% cycling Coulombic efficiency. For LIB applications (volumetric) 1090 ∼2200 ∼900 The...

参考文章(109)
Wei-Jie Li, Shu-Lei Chou, Jia-Zhao Wang, Hua-Kun Liu, Shi-Xue Dou, Simply mixed commercial red phosphorus and carbon nanotube composite with exceptionally reversible sodium-ion storage Nano Letters. ,vol. 13, pp. 5480- 5484 ,(2013) , 10.1021/NL403053V
E. Peled, C. Menachem, D. Bar‐Tow, A. Melman, Improved Graphite Anode for Lithium‐Ion Batteries Chemically Bonded Solid Electrolyte Interface and Nanochannel Formation Journal of The Electrochemical Society. ,vol. 143, ,(1996) , 10.1149/1.1836372
H. Zhou, S. Zhu, M. Hibino, I. Honma, M. Ichihara, Lithium Storage in Ordered Mesoporous Carbon (CMK‐3) with High Reversible Specific Energy Capacity and Good Cycling Performance Advanced Materials. ,vol. 15, pp. 2107- 2111 ,(2003) , 10.1002/ADMA.200306125
Lifen Xiao, Yuliang Cao, Jie Xiao, Wei Wang, Libor Kovarik, Zimin Nie, Jun Liu, High capacity, reversible alloying reactions in SnSb/C nanocomposites for Na-ion battery applications Chemical Communications. ,vol. 48, pp. 3321- 3323 ,(2012) , 10.1039/C2CC17129E
Ricardo Alcántara, Juan M. Jiménez-Mateos, Pedro Lavela, José L. Tirado, Carbon black: a promising electrode material for sodium-ion batteries Electrochemistry Communications. ,vol. 3, pp. 639- 642 ,(2001) , 10.1016/S1388-2481(01)00244-2
Verónica Palomares, Montse Casas-Cabanas, Elizabeth Castillo-Martínez, Man H. Han, Teófilo Rojo, Update on Na-based battery materials. A growing research path Energy and Environmental Science. ,vol. 6, pp. 2312- 2337 ,(2013) , 10.1039/C3EE41031E
Yihang Liu, Yunhua Xu, Yujie Zhu, James N. Culver, Cynthia A. Lundgren, Kang Xu, Chunsheng Wang, Tin-coated viral nanoforests as sodium-ion battery anodes. ACS Nano. ,vol. 7, pp. 3627- 3634 ,(2013) , 10.1021/NN400601Y
Sebastian Wenzel, Takeshi Hara, Jürgen Janek, Philipp Adelhelm, Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies Energy and Environmental Science. ,vol. 4, pp. 3342- 3345 ,(2011) , 10.1039/C1EE01744F