Self-Assembly with 2,6-Bis(1-(pyridin-4-ylmethyl)-1H-1,2,3-triazol-4-yl)pyridine: Silver(I) and Iron(II) Complexes
作者： Daniel Ross , Dan Preston , James Crowley
DOI: 10.3390/MOLECULES22101762
关键词:
摘要: A new “click” ligand, 2,6-bis(1-(pyridin-4-ylmethyl)-1H-1,2,3-triazol-4-yl)pyridine (L) featuring a tridentate 2,6-bis(1,2,3-triazol-4-yl)pyridine (tripy) pocket and two pyridyl (py) units was synthesized in modest yield (42%) using the copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) reaction. The coordination chemistry of ligand with silver(I) iron(II) ions examined battery solution (1H DOSY (diffusion ordered spectroscopy) nuclear magnetic resonance (NMR), infrared absorption spectroscopies, high-resolution electrospray ionization mass spectrometry (HR-ESI-MS)), solid state (X-ray crystallography, elemental analysis) techniques. When treated ions, forms discrete [Ag(L)]+ (X−, where X− = BF4−, NO3− or SbF6−) complexes dimethyl sulfoxide (DMSO) but these crystallize as polymers. addition [Fe(H2O)6](BF4)2 to an acetonitrile expected monomeric octahedral [Fe(L)2]2+ complex treatment AgBF4 generates heterometallic linear polymer.
mdpi.com
core.ac.uk
sci-hub.se 参考文章(41)
Jonathon E. Beves, Emma L. Dunphy, Edwin C. Constable, Catherine E. Housecroft, Cameron J. Kepert, Markus Neuburger, David J. Price, Silvia Schaffner, Vectorial property dependence in bis{4′-(n-pyridyl)-2,2′:6′,2″-terpyridine}iron(ii) and ruthenium(ii) complexes with n = 2, 3 and 4 Dalton Trans.. pp. 386- 396 ,(2008) , 10.1039/B714970K
Anthony W. Addison, T. Nageswara Rao, Jan Reedijk, Jacobus van Rijn, Gerrit C. Verschoor, Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate Journal of The Chemical Society-dalton Transactions. pp. 1349- 1356 ,(1984) , 10.1039/DT9840001349
James D. Crowley, Pauline H. Bandeen, A multicomponent CuAAC “click” approach to a library of hybrid polydentate 2-pyridyl-1,2,3-triazole ligands: new building blocks for the generation of metallosupramolecular architectures Dalton Transactions. ,vol. 39, pp. 612- 623 ,(2010) , 10.1039/B911276F
Clément Schouwey, Julian J. Holstein, Rosario Scopelliti, Konstantin O. Zhurov, Konstantin O. Nagornov, Yury O. Tsybin, Oliver S. Smart, Gérard Bricogne, Kay Severin, Self-assembly of a giant molecular Solomon link from 30 subcomponents. Angewandte Chemie. ,vol. 53, pp. 11261- 11265 ,(2014) , 10.1002/ANIE.201407144
Jiajia Yang, Mohan Bhadbhade, William A. Donald, Hasti Iranmanesh, Evan G. Moore, Hong Yan, Jonathon E. Beves, Self-assembled supramolecular cages containing ruthenium(II) polypyridyl complexes Chemical Communications. ,vol. 51, pp. 4465- 4468 ,(2015) , 10.1039/C4CC10292D
Timothy R. Cook, Yao-Rong Zheng, Peter J. Stang, Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials Chemical Reviews. ,vol. 113, pp. 734- 777 ,(2013) , 10.1021/CR3002824
Yabing He, Wei Zhou, Guodong Qian, Banglin Chen, Methane storage in metal–organic frameworks Chemical Society Reviews. ,vol. 43, pp. 5657- 5678 ,(2014) , 10.1039/C4CS00032C
Valentina Bevilacqua, Mathias King, Manon Chaumontet, Marc Nothisen, Sandra Gabillet, David Buisson, Céline Puente, Alain Wagner, Frédéric Taran, Copper‐Chelating Azides for Efficient Click Conjugation Reactions in Complex Media Angewandte Chemie. ,vol. 53, pp. 5872- 5876 ,(2014) , 10.1002/ANIE.201310671
Jonathon E. Beves, David J. Bray, Jack K. Clegg, Edwin C. Constable, Catherine E. Housecroft, Katrina A. Jolliffe, Cameron J. Kepert, Leonard F. Lindoy, Markus Neuburger, David J. Price, Silvia Schaffner, Frank Schaper, Expanding the 4,4′-bipyridine ligand: Structural variation in {M(pytpy)2}2+ complexes (pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}n3n+ Inorganica Chimica Acta. ,vol. 361, pp. 2582- 2590 ,(2008) , 10.1016/J.ICA.2007.10.040
Wen Cai, Cheng‐Chao Chu, Gang Liu, Yì‐Xiáng J Wáng, None, Metal-Organic Framework-Based Nanomedicine Platforms for Drug Delivery and Molecular Imaging. Small. ,vol. 11, pp. 4806- 4822 ,(2015) , 10.1002/SMLL.201500802