Experimental Investigation of the Zn-Al-Sb System at 450 °C
作者： Zhongxi Zhu , Xuping Su , Fucheng Yin , Jianhua Wang , Changjun Wu
DOI: 10.1007/S11669-009-9582-2
关键词:
摘要: Phase diagram of the Zn-V-Sb ternary system has been studied experimentally by means scanning electron microscopy coupled with energy-dispersive spectrometric and x-ray diffraction. Twelve different tri-phase regions could be confirmed in this at 450 °C. Moreover, a new compound named VZnSb, whose composition range spanned from 30.4-32.4 at.% V, 30.5-34.0 Zn 34.7-37.1 Sb, is positively identified for first time, crystal structure VZnSb not resolved. The phase equilibrated V3Sb, SbZn, Sb2Zn3, Sb3Zn4 η-Zn. Experimental results indicated that solubility V Sb3Zn4, Sb2Zn3 α-Sb very limited. On other hand, maximum VSb2, VSb V3Sb up to 1.8, 9.1 3.7 at.%, respectively. Sb VZn3 0.4 η-Zn dissolves 1.3 2.0 Sb.
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J.D. Donaldson, A. Kjekshus, D.G. Nicholson, T. Rakke, Properties of TiSb2 and VSb2 Journal of the Less Common Metals. ,vol. 41, pp. 255- 263 ,(1975) , 10.1016/0022-5088(75)90032-6
Zhi Li, Xuping Su, Yuehui He, 450 °C isothermal section of the Zn–Fe–Bi ternary phase diagram Journal of Alloys and Compounds. ,vol. 462, pp. 320- 327 ,(2008) , 10.1016/J.JALLCOM.2007.08.029
A.V. Tkachuk, Yu.K. Gorelenko, Yu.V. Stadnyk, O.I. Bodak, V–Mn–{Sn,Sb} ternary systems Journal of Alloys and Compounds. ,vol. 317, pp. 280- 283 ,(2001) , 10.1016/S0925-8388(00)01348-7
N. Pistofidis, G. Vourlias, S. Konidaris, E. Pavlidou, A. Stergiou, G. Stergioudis, Microstructure of zinc hot-dip galvanized coatings used for corrosion protection Materials Letters. ,vol. 60, pp. 786- 789 ,(2006) , 10.1016/J.MATLET.2005.10.013
Svend Erik Rasmussen, Rita Grønbæk Hazell, PREPARATION OF SINGLE PHASES AND SINGLE CRYSTALS IN THE VANADIUM-GALLIUM-ANTIMONY SYSTEM. CRYSTAL STRUCTURE OF V6GASB Acta Chemica Scandinavica. ,vol. 10, pp. 785- 788 ,(1978) , 10.3891/ACTA.CHEM.SCAND.32A-0785
B. Grison, P. A. Beck, The crystal structure of VSb Acta Crystallographica. ,vol. 15, pp. 807- 808 ,(1962) , 10.1107/S0365110X62002108
Siyuan Peng, Meiliang Chen, Zhongxi Zhu, Wenbo Ma, Xinming Wang, Fucheng Yin, Experimental investigation of the Zn–Fe–V system at 450°C International Journal of Materials Research. ,vol. 101, pp. 1476- 1483 ,(2010) , 10.3139/146.111349
L. A. Zabdyr, A new thermodynamic study of the liquid Sb-Zn and Cd-Sb-Zn alloys Journal of Phase Equilibria. ,vol. 13, pp. 130- 135 ,(1992) , 10.1007/BF02667473
David Schiferl, 50‐kilobar gasketed diamond anvil cell for single‐crystal x‐ray diffractometer use with the crystal structure of Sb up to 26 kilobars as a test problem Review of Scientific Instruments. ,vol. 48, pp. 24- 30 ,(1977) , 10.1063/1.1134861
A.R. Marder, The metallurgy of zinc-coated steel Progress in Materials Science. ,vol. 45, pp. 191- 271 ,(2000) , 10.1016/S0079-6425(98)00006-1