Asymmetric epoxidation of olefins with chiral bioinspired manganese complexes.
作者： Mei Wu , Bin Wang , Shoufeng Wang , Chungu Xia , Wei Sun
DOI: 10.1021/OL901400M
关键词:
摘要: A novel series of chiral tetradentate N4 ligands together with their manganese complexes have been designed and synthesized. With 1 mol % catalyst loading, the enantioselective epoxidation olefins proceeds nearly full conversion enantiomeric excess values up to 89 for first time.
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