Mechanistic Implications of the Observation of Kinetic Resolution in a Palladium-Catalyzed Enantioselective Allylic Alkylation
作者： Shailesh Ramdeehul , Peter Dierkes , Rafael Aguado , Paul C. J. Kamer , Piet W. N. M van Leeuwen
DOI: 10.1002/(SICI)1521-3773(19981204)37:22<3118::AID-ANIE3118>3.0.CO;2-G
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摘要: Preferential rotation in substrate-palladium intermediates a catalyzed asymmetric allylic alkylation is proposed to be responsible for both the observed kinetic resolution of racemic acetate starting material as well high selectivity found enantiodiscriminating product-forming step [Eq. (a)].
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