The Reactivity of Arylphosphorus Acid Amides Under Birch Reduction Conditions
作者： Marek Stankevič , Adam Włodarczyk , Damian Nieckarz
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摘要: Several classes of arylphosphorus acid amides have been tested in reactions with alkali metal solutions liquid ammonia. The outcomes such depend on the structures starting materials. Generally, two processes – Birch reduction or cleavage P–aryl bond can be operative. Diarylphosphinic tend to undergo double afford bis(cyclohexadienyl)phosphinic amides.
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