The influence of exchangeable cations on the carbonization of biomass

作者: William F. DeGroot , Fred Shafizadeh

DOI: 10.1016/0165-2370(84)80019-4

关键词:

摘要: Abstract Cations of calcium and potassium added to wood through ion exchange have unique effects on the thermal decomposition wood. Addition ions increases temperature affects char yield only slightly, while addition reduces significantly yield. These are distinct from salts same elements or similar materials absorption a solution salt. For instance, carbonate absorbed cellulose its temperature, although it has opposite effect when exchange. The primary sites for believed be glucuronic acids in hemicellulose fraction, is therefore likely that exchanged cations due primarily their influence this component. When naturally occuring inorganic species removed by acid washing, reduced cellular structure can lost during carbonization, particularly at high heating rates.

参考文章(5)
William F. DeGroot, Fred Shafizadeh, Kinetics of gasification of Douglas Fir and Cottonwood chars by carbon dioxide Fuel. ,vol. 63, pp. 210- 216 ,(1984) , 10.1016/0016-2361(84)90039-5
F. Shafizadeh, G.D. McGinnis, Chemical composition and thermal analysis of cottonwood Carbohydrate Research. ,vol. 16, pp. 273- 277 ,(1971) , 10.1016/S0008-6215(00)81161-1
Yuki Sekiguchi, Fred Shafizadeh, The effect of inorganic additives on the formation, composition, and combustion of cellulosic char Journal of Applied Polymer Science. ,vol. 29, pp. 1267- 1286 ,(1984) , 10.1002/APP.1984.070290421
R.D. Mehta, A.K.M. Mansurul Hoque, Communication to the Editor: Flammability of Metal-Cation-Exchanged Jute Fabrics Textile Research Journal. ,vol. 52, pp. 607- 608 ,(1982) , 10.1177/004051758205200909