Biomimetic assembly and activation of [FeFe]-hydrogenases

作者: G. Berggren , A. Adamska , C. Lambertz , T. R. Simmons , J. Esselborn

DOI: 10.1038/NATURE12239

关键词:

摘要: Hydrogenases are the most active molecular catalysts for hydrogen production and uptake 1 , 2 , and could therefore facilitate the development of new types of fuel cell 3 , 4 , 5 . In [FeFe]…

参考文章(37)
Purification and Characterization John Wiley & Sons, Inc.. pp. 31- 54 ,(2006) , 10.1002/0470080124.CH3
M. Y. Darensbourg, E. J. Lyon, X. Zhao, I. P. Georgakaki, The organometallic active site of [Fe]hydrogenase: models and entatic states. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 100, pp. 3683- 3688 ,(2003) , 10.1073/PNAS.0536955100
Yvain Nicolet, Claudine Piras, Pierre Legrand, Claude E Hatchikian, Juan C Fontecilla-Camps, Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center. Structure. ,vol. 7, pp. 13- 23 ,(1999) , 10.1016/S0969-2126(99)80005-7
Jon M. Kuchenreuther, Celestine S. Grady-Smith, Alyssa S. Bingham, Simon J. George, Stephen P. Cramer, James R. Swartz, High-Yield Expression of Heterologous [FeFe] Hydrogenases in Escherichia coli PLoS ONE. ,vol. 5, pp. e15491- ,(2010) , 10.1371/JOURNAL.PONE.0015491
Michael Schmidt, Stephen M. Contakes, Thomas B. Rauchfuss, First Generation Analogues of the Binuclear Site in the Fe-Only Hydrogenases: Fe2(μ-SR)2(CO)4(CN)22- Journal of the American Chemical Society. ,vol. 121, pp. 9736- 9737 ,(1999) , 10.1021/JA9924187
James A. Cracknell, Kylie A. Vincent, Fraser A. Armstrong, Enzymes as working or inspirational electrocatalysts for fuel cells and electrolysis. Chemical Reviews. ,vol. 108, pp. 2439- 2461 ,(2008) , 10.1021/CR0680639
Alban Le Cloirec, Sian C. Davies, David J. Evans, David L. Hughes, Christopher J. Pickett, Stephen P. Best, Stacey Borg, A di-iron dithiolate possessing structural elements of the carbonyl/cyanide sub-site of the H-centre of Fe-only hydrogenase Chemical Communications. pp. 2285- 2286 ,(1999) , 10.1039/A906391I