Inkrementsystem zur Beschreibung der Lage von Ionenpaar‐Charge‐Transfer‐Banden in Wasser und nichtwäßrigen Lösungsmitteln

摘要: Increment System for Predicting of the Position Ion Pair Charge-Transfer Bands in Water and Non-aqueous Solvents The energy absorption maximum ion-pair charge-transfer bands, ΔGCT, occuring addition to absorptions single ions, is approximately sum contributions (increments) ions concerned. On basis spectroscopic data, an increment system predicting ΔGCT aqueous solution has been proposed. A linear relationship between increments standard electrode potentials found, permitting expansion system. The difference calculated experimental values does not exceed 2500 cm−1. applicability non-aqueous solvents proved several cases.