Electrochemical hydrogen storage in ironnitrogen dual-doped ordered mesoporous carbon

作者: Deyu Qu , Xiaoduo Xu , Lina Zhou , Wenjing Li , Jorryn Wu

DOI: 10.1016/J.IJHYDENE.2019.01.273

关键词:

摘要: Abstract Due to the advantage of catalytic activity on process hydrogen sorption/desorption and high affiliation with hydrogen, iron nanoparticles are a hybrid within an ordered mesoporous carbon nitrogen functional groups surface used as host for improving electrochemical storage. This dual-doped material is synthesized through nano-casting method which uses SBA-15 hard template phthalocyanine iron, source. After characterization by SEM, TEM, XRD, Raman, XPS Nitrogen measurements, this demonstrated storage capacity 120 mAh g−1. associated fast kinetics insertion, low self-discharge good cycling capability. Furthermore, stored inside composited shows excellent rate performance under various states discharge current densities. Results suggest that enhanced performances may due electro-catalytic nanoparticle, basicity nature functionality surface, large area, porosity interconnected pore structure.

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