Degree of Substitution of Dextran Modified through Reaction with Organostannane Chlorides and Group IV-B Metallocene Dichlorides
作者： Charles E. Carraher , Yoshinobu Naoshima
DOI: 10.1007/978-1-4615-3844-8_13
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摘要: Dextrans represent a potential market of 2 × 105 tons per year. Reaction with Groups IV-A and B organoraetallics show distinct trends respect to loading or presence organometallic moiety repeat sugar unit. For Group IV-B metallocene dichlorides, can be easily varied from less than one unit full loading, presumably due the lack tendency form cyclic products. By comparison, organostannane halides is typically order 0.25 0.5 tin dilhalides internal formation probably occurs major extent limiting loading. Use selected PTAs allows organostannanes increased two tins
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sci-hub.st 参考文章(18)
John E. Sheats, Charles U. Pittman, Charles E. Carraher, Metal-Containing Polymeric Systems ,(1985)
Applied bioactive polymeric materials ACS Symposium on Applied Bioactive Polymeric Materials (1987 : New Orleans, La.). ,(1988) , 10.1007/978-1-4684-5610-3
L. H. Sperling, Charles E. Carraher, Polymer Applications of Renewable-Resource Materials ,(1983)
James A. Moore, Charles E. Carraher, Modification of Polymers Polymer science and technology. ,vol. 21, pp. 1- 12 ,(1980) , 10.1007/978-1-4613-3748-5_1
Mina A. Nashed, Laurens Anderson, Organotin derivatives and the selective acylation and alkylation of the equatorial hydroxy group in a vicinal, equatorial-axial pair Tetrahedron Letters. ,vol. 17, pp. 3503- 3506 ,(1976) , 10.1016/S0040-4039(00)71342-6
YOSHISUKE TSUDA, MD.ERAMUL HAQUE, KIMIHIRO YOSHIMOTO, Regioselective Monoacylation of Some Glycopyranosides via Cyclic Tin Intermediates Chemical & Pharmaceutical Bulletin. ,vol. 31, pp. 1612- 1624 ,(1983) , 10.1248/CPB.31.1612
Charles E. Carraher, Timothy J. Gehrke, David J. Giron, Delie Roselyn Cerutis, H. M. Molloy, Structure and Characterization of the Condensation Products of Dextran and Organostannane Halides Journal of Macromolecular Science: Part A - Chemistry. ,vol. 19, pp. 1121- 1135 ,(1983) , 10.1080/00222338308081089
Y Naoshima, C E Carraher, S Iwamoto, H Shudot, Synthesis of metal-containing carbohydrate polymers employing crown ether phase transfer catalyzed interfacial condensation Applied Organometallic Chemistry. ,vol. 1, pp. 245- 249 ,(1987) , 10.1002/AOC.590010306
Mina A. Nashed, An improved method for selective substitution on O-3 of D-mannose. Application to the synthesis of methyl 3-O-methyl-and 2-O-α-Dmannopyranosides Carbohydrate Research. ,vol. 60, pp. 200- 205 ,(1978) , 10.1016/S0008-6215(00)83479-5
Tomoya Ogawa, Masanao Matsui, A new approach to regioselective acylation of polyhydroxy compounds Carbohydrate Research. ,vol. 56, pp. c1- c6 ,(1977) , 10.1016/S0008-6215(00)84258-5