作者: Davorka Azinović , Xinghua Li , Slobodan Milošević , Goran Pichler , Marc C. van Hemert
DOI: 10.1063/1.464971
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摘要: Electronically excited NaZn excimers have been produced in a photochemical reaction of Na2(C 1Πu) with Zn(4 1S0). The Na–Zn vapor mixture was prepared by introducing controlled stream sodium into zinc generated heat‐pipe oven. A new band (bound–free transition) observed the region from 450 to 487 nm. Potential curves eight lowest electronic states were calculated. On basis calculations, emission is interpreted as resulting 2 2Π–X 2Σ+ transition. conditions favorable for observation are discussed.