Das 4-Methoxyanilin-Radikalkation, eingeschränkte Rotation um die O-Phenyl-Bindung
作者： Stephan Bamberger , Franz Alfred Neugebauer , Jorge Valenzuela
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摘要: Das 4-Methoxyanilin-Radikalkation 2 und die Derivate 3 4 wurden in Trifluoressigsaure durch Oxidation der entsprechenden Arylamine mit Bleitetraacetat erzeugt. Ihre ESR-Spektren zeigen eine eingeschrankte Rotation um O-Phenyl-Bindung. The 4-Methoxyaniline Radical Cation, Restricted around the O-Phenyl Bond The 4-methoxyaniline radical cation and derivatives were generated trifluoroacetic acid by oxidation of parent arylamines with lead tetraacetate. Their e. s. r. spectra show a restricted rotation O-phenyl bond.
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