Mesoporous carbon-supported Pd nanoparticles with high specific surface area for cyclohexene hydrogenation: Outstanding catalytic activity of NaOH-treated catalysts
作者： Róbert Puskás , Tamás Varga , Andor Grósz , András Sápi , A Oszkó
DOI: 10.1016/J.SUSC.2015.12.020
关键词:
摘要: Abstract Extremely high specific surface area mesoporous carbon-supported Pd nanoparticle catalysts were prepared with both impregnation and polyol-based sol methods. The silica template used for the synthesis of carbon was removed by NaOH HF etching. Pd/mesoporous synthesized method has as 2250 m 2 /g. In case NaOH-etched impregnated samples, turnover frequency cyclohexene hydrogenation to cyclohexane at 313 K obtained ~ 14 molecules ∙ site − 1 ∙ s . HF-etched samples higher compared samples. However, catalytic activity ~ 3–6 times on which can be attributed presence sodium hydroxylgroups etched solution.
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