Synthesis and thermal properties of a novel high temperature alkyl-center-trisphenolic-based phthalonitrile polymer
作者： Haitong Sheng , Xuegang Peng , Hui Guo , Xiaoyan Yu , Chengchun Tang
DOI: 10.1016/J.MATCHEMPHYS.2013.08.033
关键词:
摘要: Abstract A novel alkyl-center-trisphenolic-based high-temperature phthalonitrile monomer, namely, 1,1,1-tris-[4-(3,4-dicyanophenoxy)phenyl]ethane (TDPE), was synthesized from 1,1,1-tris-(4-hydroxyphenyl)ethane (THPE) via a facile nucleophilic displacement of nitro-substituent 4-nitrophthalonitrile (NPN). The structure TDPE monomer characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (1H and 13C NMR), elemental analysis (EA). Curing behaviors with 4-(aminophenoxy)phthalonitrile (APPH) were recorded differential scanning calorimetric (DSC) it showed large processing window (122 °C) which is favorable to polymers. polymer discussed the thermal stabilities evaluated thermogravimetric (TGA). exhibits excellent stability, mechanism decompositions explored. Dynamic mechanical (DMA) revealed that has high storage modulus glass transition temperature (Tg > 380 °C).
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Malay K. Ghosh, K. L. Mittal, Polyimides: Fundamentals and Applications ,(1996)
Paul M. Hergenrother, The Use, Design, Synthesis, and Properties of High Performance/High Temperature Polymers: An Overview High Performance Polymers. ,vol. 15, pp. 3- 45 ,(2003) , 10.1177/095400830301500101
Dawn D. Dominguez, Teddy M. Keller, Low-melting Phthalonitrile Oligomers: Preparation, Polymerization and Polymer Properties: High Performance Polymers. ,vol. 18, pp. 283- 304 ,(2006) , 10.1177/0954008306060143
C. S. Marvel, Michael M. Martin, Polymeric Phthalocyanines. II1 Journal of the American Chemical Society. ,vol. 80, pp. 6600- 6604 ,(1958) , 10.1021/JA01557A037
John P. Droske, John K. Stille, William B. Alston, Biphenylene end-capped polyquinoline and polyimide prepolymers as matrix resins for high-use-temperature composites Macromolecules. ,vol. 17, pp. 14- 18 ,(1984) , 10.1021/MA00131A003
Xiaoli Yang, Jiandong Zhang, Yajie Lei, Jiachun Zhong, Xiaobo Liu, Effect of Different Aromatic Amines on the Crosslinking Behavior and Thermal Properties of Phthalonitrile Oligomer Containing Biphenyl Ethernitrile Journal of Applied Polymer Science. ,vol. 121, pp. 2331- 2337 ,(2011) , 10.1002/APP.33949
Wei Xie, Zongming Gao, Wei-Ping Pan, Doug Hunter, Anant Singh, Richard Vaia, Thermal Degradation Chemistry of Alkyl Quaternary Ammonium Montmorillonite Chemistry of Materials. ,vol. 13, pp. 2979- 2990 ,(2001) , 10.1021/CM010305S
Teddy M Keller, Imide-containing phthalonitrile resin Polymer. ,vol. 34, pp. 952- 955 ,(1993) , 10.1016/0032-3861(93)90213-T
Satya B. Sastri, Teddy M. Keller, Phthalonitrile polymers: Cure behavior and properties Journal of Polymer Science Part A. ,vol. 37, pp. 2105- 2111 ,(1999) , 10.1002/(SICI)1099-0518(19990701)37:13<2105::AID-POLA25>3.0.CO;2-A