Synthesis of silver nanoparticles in a polyvinylpyrrolidone (PVP) paste, and their optical properties in a film and in ethylene glycol
作者： A. Slistan-Grijalva , R. Herrera-Urbina , J.F. Rivas-Silva , M. Ávalos-Borja , F.F. Castillón-Barraza
DOI: 10.1016/J.MATERRESBULL.2007.02.013
关键词:
摘要: Abstract Silver nanoparticles were synthesized in a paste of polyvinylpyrrolidone formed after mixing PVP with acetone and small volume aqueous silver nitrate under magnetic stirring. A film made the material was characterized by UV–vis spectroscopy. The obtained spectrum shows single peak at 438 nm, arising from surface plasmon absorption colloids. This result clearly indicates that are embedded PVP. When pre-treated PVP–Ag colloid is dissolved ethylene glycol, resulting dispersion an 433 nm, whose maximum blue shifts to 416 nm 18 days agitation. have average particle size 4.12 nm. Because IR band assigned carbonyl group longer wavelengths, interaction this polymer seems take place through oxygen.
elsevier.com
sci-hub.se 参考文章(24)
Craig F. Bohren, Donald R. Huffman, Absorption and Scattering of Light by Small Particles ,(1983)
David C. Skillman, Chester R. Berry, Effect of Particle Shape on the Spectral Absorption of Colloidal Silver in Gelatin Journal of Chemical Physics. ,vol. 48, pp. 3297- 3304 ,(1968) , 10.1063/1.1669607
Paul Mulvaney, Surface Plasmon Spectroscopy of Nanosized Metal Particles Langmuir. ,vol. 12, pp. 788- 800 ,(1996) , 10.1021/LA9502711
Yugang Sun, Younan Xia, Shape-Controlled Synthesis of Gold and Silver Nanoparticles Science. ,vol. 298, pp. 2176- 2179 ,(2002) , 10.1126/SCIENCE.1077229
G. Carotenuto, G.P. Pepe, L. Nicolais, Preparation and characterization of nano-sized Ag/PVP composites for optical applications European Physical Journal B. ,vol. 16, pp. 11- 17 ,(2000) , 10.1007/S100510070243
Yugang Sun, Byron Gates, Brian Mayers, Younan Xia, Crystalline Silver Nanowires by Soft Solution Processing Nano Letters. ,vol. 2, pp. 165- 168 ,(2002) , 10.1021/NL010093Y
Benjamin Wiley, Thurston Herricks, Yugang Sun, Younan Xia, Polyol Synthesis of Silver Nanoparticles: Use of Chloride and Oxygen to Promote the Formation of Single-Crystal, Truncated Cubes and Tetrahedrons Nano Letters. ,vol. 4, pp. 1733- 1739 ,(2004) , 10.1021/NL048912C
Isabel Pastoriza-Santos, Luis M. Liz-Marzán, Formation of PVP-Protected Metal Nanoparticles in DMF Langmuir. ,vol. 18, pp. 2888- 2894 ,(2002) , 10.1021/LA015578G
Xue-feng Qian, Jie Yin, Shuang Feng, Shu-hong Liu, Zi-kang Zhu, Preparation and characterization of polyvinylpyrrolidone films containing silver sulfide nanoparticles Journal of Materials Chemistry. ,vol. 11, pp. 2504- 2506 ,(2001) , 10.1039/B103708K
A. Slistan-Grijalva, R. Herrera-Urbina, J.F. Rivas-Silva, M. Ávalos-Borja, F.F. Castillón-Barraza, A. Posada-Amarillas, Classical theoretical characterization of the surface plasmon absorption band for silver spherical nanoparticles suspended in water and ethylene glycol Physica E-low-dimensional Systems & Nanostructures. ,vol. 27, pp. 104- 112 ,(2005) , 10.1016/J.PHYSE.2004.10.014