Brominated thiophenes as precursors in the preparation of brominated and arylated anthraquinones.

作者: Thies Thiemann , Yasuko Tanaka , Jesus Iniesta

DOI: 10.3390/MOLECULES14031013

关键词:

摘要: Brominated anthraquinones can be synthesized directly from bromothiophenes when these are reacted with 1,4-naphthoquinones in the presence of meta-chloroperoxybenzoic acid. The bromoanthraquinones versatile building blocks preparation arylated and extended π-systems interspersed anthraquinone units.

参考文章(39)
Bernd Zeeh, Herbert Meier, Manfred Hesse, Spectroscopic Methods in Organic Chemistry ,(2007)
Yuanqiang Li, Michio Matsuda, Thies Thiemann, Tsuyoshi Sawada, Shuntaro Matake, Masashi Tashiro, None, Lewis Acid-Catalysed Oxidative Cycloaddition of Thiophenes1 Synlett. ,vol. 1996, pp. 461- 464 ,(1996) , 10.1055/S-1996-5446
David P. G. Hamon, Paul R. Spurr, A simple construction of the iceane skeleton via an intramolecular Diels–Alder reaction Journal of The Chemical Society, Chemical Communications. pp. 372- 373 ,(1982) , 10.1039/C39820000372
Hans Wynberg, R. Helder, A one-step ring enlargement of a thiophene to a thiepin Tetrahedron Letters. ,vol. 13, pp. 3647- 3650 ,(1972) , 10.1016/S0040-4039(01)94124-3
Naomichi Furukawa, Shao-Zhong Zhang, Ernst Horn, Ohgi Takahashi, Soichi Sato, Masataka Yokoyama, Kentaro Yamaguchi, X-ray crystallographic analysis of 2,5-bis(diphenylmethylsilyl)thiophene monooxide and the diels-alder reaction of thiophene monooxide with dienophiles Heterocycles. ,vol. 47, pp. 793- 809 ,(1998) , 10.3987/COM-97-S(N)80
H.D. Hollis Showalter, Ellen M. Berman, Judith L. Johnson, Jerry L. Atwood, William E. Hunter, A facile synthesis of functionalized 9,10- anthracenediones via tosylate and triflate phenolic activation Tetrahedron Letters. ,vol. 26, pp. 157- 160 ,(1985) , 10.1016/S0040-4039(00)61868-3
Julien E. Gautrot, Philip Hodge, Domenico Cupertino, Madeleine Helliwell, Experimental evidence for carbonyl–π electron cloud interactions New Journal of Chemistry. ,vol. 30, pp. 1801- 1807 ,(2006) , 10.1039/B608628D
Pascale Pouzet, Irene Erdelmeier, Daria Ginderow, Patrick M. Dansette, Daniel Mansuy, Jean-Paul Mornon, Thiophene 1-oxides. V. Comparison of the crystal structures and thiophene ring aromaticity of 2,5-diphenylthiophene, its sulfoxide and sulfone†‡§¶ Journal of Heterocyclic Chemistry. ,vol. 34, pp. 1567- 1574 ,(1997) , 10.1002/JHET.5570340530
Nina Gjøs, Salo Gronowitz, Ole Buchardt, Bodil Jerslev, Claus Erik Schäffer, Erling Sunde, Nils Andreas Sørensen, Some Substitution Reactions of 3-Phenylthiophene. Acta Chemica Scandinavica. ,vol. 24, pp. 99- 104 ,(1970) , 10.3891/ACTA.CHEM.SCAND.24-0099