A New Method of Quantitative Differential Thermal Analysis

摘要: This paper presents a rigorous new theory of differential thermal analysis, taking account the temperature gradient in sample. From this consideration, quantitative method is proposed, where solid-cell holder low conductivity set between sample cell and metal block, thermocouple inserted tightly outside wall holder. By means arrangement, peak area becomes proportional to heat transformation, irrespective kinds states samples operational variables. The experimental verification using various effect several variables, such as heating rate, concentration diluent, packing density, depth sample, are also shown; satisfactory results obtained. Two concepts, sensitivity response time system, proposed evaluated. Conventional methods criticized, inherent limitations differential...