Selective adsorption and decomposition of pollutants using RGO-TiO2 with optimized surface functional groups

作者: Yunfei Sun , Yanfeng He , Bo Tang , Zhengtian Wu , Chongben Tao

DOI: 10.1039/C8RA05345F

关键词:

摘要: Reduced graphene oxide (RGO) samples with optimized types of surface functional groups were hybridized TiO2 to achieve the selective adsorption and removal various pollutants. A high ratio hydroxyl was found be remarkably advantageous for adsorbtion decomposition rhodamine-B (and similar pollutants), while a carboxyl promote ability adsorb decompose phenol. Moreover, presence on RGO edge provides pre-condition form close chemical connection TiO2, which has been proven by obtained electron paramagnetic resonance (EPR) curve, infrared spectroscopy (IR) lifetime. The resulting composite photocatalysts display excellent photocatalytic activities under both UV- visible-light illumination, indicating that well-designed micro-circumstances are quite significant.

参考文章(26)
Guoxin Zhang, Yuqi Xu, Lin Wang, Jindi Wang, Yun Kuang, Xiaoming Sun, Rational design of graphene oxide and its hollow CoO composite for superior oxygen reduction reaction Science China Materials. ,vol. 58, pp. 534- 542 ,(2015) , 10.1007/S40843-015-0064-Z
Hao Zhang, Xiaojun Lv, Yueming Li, Ying Wang, Jinghong Li, P25-Graphene Composite as a High Performance Photocatalyst ACS Nano. ,vol. 4, pp. 380- 386 ,(2010) , 10.1021/NN901221K
Bernhard Neumann, Peter Bogdanoff, Helmut Tributsch, Shanmugasundaram Sakthivel, Horst Kisch, Electrochemical mass spectroscopic and surface photovoltage studies of catalytic water photooxidation by undoped and carbon-doped titania. Journal of Physical Chemistry B. ,vol. 109, pp. 16579- 16586 ,(2005) , 10.1021/JP051339G
Qi Xiao, Jiang Zhang, Chong Xiao, Zhichun Si, Xiaoke Tan, Solar photocatalytic degradation of methylene blue in carbon-doped TiO2 nanoparticles suspension Solar Energy. ,vol. 82, pp. 706- 713 ,(2008) , 10.1016/J.SOLENER.2008.02.006
Michael R. Hoffmann, Scot T. Martin, Wonyong. Choi, Detlef W. Bahnemann, Environmental Applications of Semiconductor Photocatalysis Chemical Reviews. ,vol. 95, pp. 69- 96 ,(1995) , 10.1021/CR00033A004
William S. Hummers, Richard E. Offeman, Preparation of graphitic acid Journal of the American Chemical Society. ,vol. 80, pp. 1339- 1339 ,(1954) , 10.1021/JA01539A017
Chao Chen, Weimin Cai, Mingce Long, Baoxue Zhou, Yahui Wu, Deyong Wu, Yujie Feng, Synthesis of visible-light responsive graphene oxide/TiO(2) composites with p/n heterojunction. ACS Nano. ,vol. 4, pp. 6425- 6432 ,(2010) , 10.1021/NN102130M
Yunfei Sun, Bo Tang, Weiqiu Huang, Shuli Wang, Zhengwei Wang, Xiaobin Wang, Yuejin Zhu, Chongben Tao, Preparation of graphene modified epoxy resin with high thermal conductivity by optimizing the morphology of filler Applied Thermal Engineering. ,vol. 103, pp. 892- 900 ,(2016) , 10.1016/J.APPLTHERMALENG.2016.05.005