Palladium catalysts for aerobic oxidative kinetic resolution of secondary alcohols based on mechanistic insight.

作者: David R. Jensen , Matthew S. Sigman

DOI: 10.1021/OL027190Y

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摘要: … In this framework, we reported an aerobic oxidative kinetic resolution of secondary alcohols using (−)-sparteine, Pd(II), and O 2 . A significant limitation of this system is the requirement …

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