Catalyst structure and substituent effects on epoxidation of styrenics with immobilized Mn(tmtacn) complexes

作者: Patricia Anne A. Ignacio-de Leon , Christian A. Contreras , Nicholas E. Thornburg , Anthony B. Thompson , Justin M. Notestein

DOI: 10.1016/J.APCATA.2015.12.002

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摘要: … acidity of benzoic acid (pK a 4.19 for benzoic acid vs. 4.86 for propanoic acid) [68] favors the formation of the Mn-carboxylate complex [67], … We find that the immobilized benzoic acid co-…

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