ZnO thin films growth by pulsed vacuum arc discharge

作者: E. Restrepo-Parra , L.E. Moreno-Montoya , P.J. Arango-Arango

DOI: 10.1016/J.SURFCOAT.2009.07.020

关键词:

摘要: Abstract A study of structural and morphologic features ZnO coatings grown by pulsed vacuum arc discharge is presented in this work. The characteristics the plasma generated during production process are determined using Optical Emission Spectroscopy technique. system employed for growing films consists a chamber with two opposite electrodes (the cathode target zinc anode substrate glass). gas used filling reactor was high purity oxygen. at pressure 200 Pa voltage 200 V. Coatings were characterized X-ray diffraction scanning probe microscopy (SPM) techniques. XRD patterns showed hexagonal crystalline structure peaks produced planes (002) (103). roughness observed 98.6 nm. No great quantity nanodroppers on surface. Plasma spectroscopic studies revealed many lines belonging to different species like Zn (328.2, 330.3, 334.5 nm), + (491.3 492.5 nm), O (372 nm) (336.1, 337.25 518 nm) weak bands (526.47, 531.2, 536.94 nm). presence an important finding because, techniques, authors have reported as being exclusively surface not into plasma. electron temperature ( T e ) density n means methods such relation between same ionization state calculation Stark Broadening .

参考文章(54)
M. S. Dimitrijević, Stark Broadening of Ne II and Ne III Spectral Lines Journal of Applied Spectroscopy. ,vol. 70, pp. 493- 497 ,(2003) , 10.1023/A:1026181410196
A. G. Gaydon, R. W. B. Pearse, The identification of molecular spectra ,(1950)
M. K. Puchert, P. Y. Timbrell, R. N. Lamb, Postdeposition annealing of radio frequency magnetron sputtered ZnO films Journal of Vacuum Science and Technology. ,vol. 14, pp. 2220- 2230 ,(1996) , 10.1116/1.580050
Alfonso Devia Cubillos, Elisabeth Restrepo Parra, Belarmino Segura Giraldo, Yulieth Cristina Arango, Diego Fernando Arias Mateus, Study of TiN and Ti/TiN coatings produced by pulsed-arc discharge Surface & Coatings Technology. ,vol. 190, pp. 83- 89 ,(2005) , 10.1016/J.SURFCOAT.2004.07.082
H Kelly, A Márquez, F Minotti, C Ferro Fontán, The plasma state in the surroundings of a multi-cathode-spot vacuum arc Journal of Physics D. ,vol. 31, pp. 1737- 1741 ,(1998) , 10.1088/0022-3727/31/14/018
V. Fisher, V. Bernshtam, H. Golten, Y. Maron, Electron-impact excitation cross sections for allowed transitions in atoms Physical Review A. ,vol. 53, pp. 2425- 2432 ,(1996) , 10.1103/PHYSREVA.53.2425
B.M Ataev, A.M Bagamadova, V.V Mamedov, A.K Omaev, Thermally stable, highly conductive, and transparent ZnO layers prepared in situ by chemical vapor deposition Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 65, pp. 159- 163 ,(1999) , 10.1016/S0921-5107(99)00166-X
K.S. Suraj, P. Bharathi, V. Prahlad, S. Mukherjee, Near cathode optical emission spectroscopy in N2-H2 glow discharge plasma Surface & Coatings Technology. ,vol. 202, pp. 301- 309 ,(2007) , 10.1016/J.SURFCOAT.2007.05.063
T. Mazingue, L. Escoubas, L. Spalluto, F. Flory, G. Socol, C. Ristoscu, E. Axente, S. Grigorescu, I. N. Mihailescu, N. A. Vainos, Nanostructured ZnO coatings grown by pulsed laser deposition for optical gas sensing of butane Journal of Applied Physics. ,vol. 98, pp. 074312- ,(2005) , 10.1063/1.2076442