The use of barium (II) to promote triplet←singlet transitions in organic compounds; an external heavy-atom effect
作者： Ana Maria P.C. de Amorim , Hugh D. Burrows , Sebastiáo J. Formosinho , Abílio M. da Silva
DOI: 10.1016/0584-8539(77)80024-X
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摘要: Abstract The possibility of using barium (II) to promote spin forbidden transitions is examined. Methanolic solutions both quinoline and naphthalene in the presence perchlorate reveal weak bands their electronic absorption spectra which are assigned lowest triplet←singlet transitions. Barium also found quench fluorescence naphthalene, probably as a result heavy atom effect.
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sci-hub.se 参考文章(4)
S. P. McGlynn, T. Azumi, M. Kasha, External Heavy‐Atom Spin—Orbital Coupling Effect. V. Absorption Studies of Triplet States Journal of Chemical Physics. ,vol. 40, pp. 507- 515 ,(1964) , 10.1063/1.1725145
D. F. Evans, 552. Magnetic perturbation of singlet–triplet transitions. Part III. Benzene derivatives and heterocyclic compounds Journal of The Chemical Society (resumed). pp. 2753- 2757 ,(1959) , 10.1039/JR9590002753
E.Vander Donckt, C. Vogels, Substituent effects an singlet-triplet absorption spectra Spectrochimica Acta Part A: Molecular Spectroscopy. ,vol. 27, pp. 2157- 2163 ,(1971) , 10.1016/0584-8539(71)80115-0
Larry K. Patterson, Stefan J. Rzad, Quenching of aromatic hydrocarbon fluorescence by cesium chloride Chemical Physics Letters. ,vol. 31, pp. 254- 256 ,(1975) , 10.1016/0009-2614(75)85015-9