Effect of morphology on the interfacial slip of immiscible polypropylene/polystyrene blends

作者: Ming Wang , Jiabin Shen , Jiang Li , Shaoyun Guo

DOI: 10.1007/S00397-013-0725-3

关键词:

摘要: The interfacial slip of the immiscible isotactic polypropylene/polystyrene (PS) blends with different morphologies was studied. were obtained by choosing PS contents (7, 21, and 55 vol%) processing methods (multilayered co-extrusion conventional blending). obviously found in multilayered morphology co-continuous morphology, but did not occur sea-island morphology. Besides, it observed that velocity system higher than could be promoted increase layer numbers. However, would suppressed deformation breaking during test, when thickness layers thin enough. effect composition on also discussed composites.

参考文章(24)
Y. Jin, A. Hiltner, E. Baer, Fractionated crystallization of polypropylene droplets produced by nanolayer breakup Journal of Polymer Science Part B. ,vol. 45, pp. 1138- 1151 ,(2007) , 10.1002/POLB.21146
L. Jiang, Y. C. Lam, J. Zhang, Rheological properties and interfacial slip of a multilayer structure under dynamic shear Journal of Polymer Science Part B. ,vol. 43, pp. 2683- 2693 ,(2005) , 10.1002/POLB.20557
Hiroshi Furukawa, Sliding along the interface of strongly segregated polymer melts Physical Review A. ,vol. 40, pp. 6403- 6406 ,(1989) , 10.1103/PHYSREVA.40.6403
Jiabin Shen, Ming Wang, Jiang Li, Shaoyun Guo, In situ fibrillation of polyamide 6 in isotactic polypropylene occurring in the laminating-multiplying die Polymers for Advanced Technologies. ,vol. 22, pp. 237- 245 ,(2011) , 10.1002/PAT.1525
Shuangxi Xu, Ming Wen, Jiang Li, Shaoyun Guo, Ming Wang, Qin Du, Jiabin Shen, Yuqing Zhang, Songling Jiang, None, Structure and properties of electrically conducting composites consisting of alternating layers of pure polypropylene and polypropylene with a carbon black filler Polymer. ,vol. 49, pp. 4861- 4870 ,(2008) , 10.1016/J.POLYMER.2008.08.056
M. Bousmina, Hua Qiu, M. Grmela, J. E. Klemberg-Sapieha, Diffusion at Polymer/Polymer Interfaces Probed by Rheological Tools Macromolecules. ,vol. 31, pp. 8273- 8280 ,(1998) , 10.1021/MA980562R
T. Schuman, E. V. Stepanov, S. Nazarenko, G. Capaccio, A. Hiltner, E. Baer, Interdiffusion of Linear and Branched Polyethylene in Microlayers Studied via Melting Behavior Macromolecules. ,vol. 31, pp. 4551- 4561 ,(1998) , 10.1021/MA971758E
Leon Levitt, Christopher W. Macosko, Shearing of Polymer Drops with Interface Modification Macromolecules. ,vol. 32, pp. 6270- 6277 ,(1999) , 10.1021/MA9814999
Jiabin Shen, Ming Wang, Jiang Li, Shaoyun Guo, Shuangxi Xu, Yuqing Zhang, Ting Li, Ming Wen, Simulation of mechanical properties of multilayered propylene–ethylene copolymer/ethylene 1-octene copolymer composites by equivalent box model and its experimental verification European Polymer Journal. ,vol. 45, pp. 3269- 3281 ,(2009) , 10.1016/J.EURPOLYMJ.2009.07.013
Rui Zhao, Christopher W. Macosko, Slip at polymer–polymer interfaces: Rheological measurements on coextruded multilayers Journal of Rheology. ,vol. 46, pp. 145- 167 ,(2002) , 10.1122/1.1427912