Crystallized material with hierarchical porosity containing silicon

作者: Cedric Boissiere , Clement Sanchez , Aurelie Coupe , Alexandra Chaumonnot

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摘要: Hierarchical porosity material consisting of at least two elementary spherical particles having a maximum diameter 200 microns, one said comprises matrix based on silicon oxide and exhibiting crystallized walls, macropore volume measured by mercury porosimetry ranging between 0.05 1 ml/g, mesopore nitrogen volumetric analysis 0.01 ml/g micropore 0.03 0.4 ml/g. The preparation use same as adsorbent or acidic solid is also described.

参考文章(13)
Ruth Ann Doyle, Jeffrey T. Miller, Bryce A. Williams, Para-xylene selective adsorbent compositions and methods ,(2004)
Chantal Rigaill, Geraldine Laborie, Fabrice LeComte, Michel Thomas, Eszter Toth, Method of purifying a natural gas by mercaptan adsorption ,(2006)
Albert E. Schweizer, Keith Holroyd Kuechler, Stephen Neil Vaughn, Luc Roger Marc Martens, Synthesis of molecular sieve catalysts ,(2001)
Luigi Balducci, Roberto Buzzoni, Leonardo Dalloro, Alberto Cesana, Process for the preparation of MFI-Type zeolitic catalysts ,(2002)
Baojian Zhang, Sean A. Davis, Stephen Mann, Starch gel templating of spongelike macroporous silicalite monoliths and mesoporous films Chemistry of Materials. ,vol. 14, pp. 1369- 1375 ,(2002) , 10.1021/CM011251P
Valeri Naydenov, Lubomira Tosheva, Johan Sterte, Self-Bonded Zeolite Beta/MCM-41 Composite Spheres Journal of Porous Materials. ,vol. 12, pp. 193- 199 ,(2005) , 10.1007/S10934-005-1647-Y
Valentin P. Valtchev, Monique Smaihi, Anne-Catherine Faust, Loic Vidal, Equisetum arvense Templating of Zeolite Beta Macrostructures with Hierarchical Porosity Chemistry of Materials. ,vol. 16, pp. 1350- 1355 ,(2004) , 10.1021/CM035100T
Ryoji TAKAHASHI, Satoshi SATO, Toshiaki SODESAWA, Hironobu NISHINO, Akiyuki YACHI, Synthesis of Monolithic Zeolites with Macropores Journal of the Ceramic Society of Japan. ,vol. 114, pp. 421- 424 ,(2006) , 10.2109/JCERSJ.114.421
Wen-Cui Li, An-Hui Lu, Regina Palkovits, Wolfgang Schmidt, Bernd Spliethoff, Ferdi Schüth, Hierarchically structured monolithic silicalite-1 consisting of crystallized nanoparticles and its performance in the Beckmann rearrangement of cyclohexanone oxime. Journal of the American Chemical Society. ,vol. 127, pp. 12595- 12600 ,(2005) , 10.1021/JA052693V
Johan C. Groen, Louk A. A. Peffer, Jacob A. Moulijn, Javier Pérez-Ramírez, Mechanism of hierarchical porosity development in MFI zeolites by desilication: the role of aluminium as a pore-directing agent. Chemistry: A European Journal. ,vol. 11, pp. 4983- 4994 ,(2005) , 10.1002/CHEM.200500045