Formaldoxime hydrogen bonded complexes with ammonia and hydrogen chloride.
作者： Barbara Golec , Małgorzata Mucha , Magdalena Sałdyka , Austin Barnes , Zofia Mielke
DOI: 10.1016/J.SAA.2013.11.017
关键词:
摘要: Abstract An infrared spectroscopic and MP2/6–311++G(2d,2p) study of hydrogen bonded complexes formaldoxime with ammonia chloride trapped in solid argon matrices is reported. Both 1:1 1:2 between ammonia, have been identified the CH2NOH/NH3/Ar, CH2NOH/HCl/Ar matrices, respectively, their structures were determined by comparison spectra results calculations. In present OH group acts as a proton donor for nitrogen atom acceptor chloride. or dimers interact both CH2NOH to form seven membered cyclic stabilized three bonds. The theoretical generally agree well experimental ones, but they seriously underestimate shift stretch CH2NOH⋯NH3 complex.
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