Synthesis of stannic(IV) complexes: Their structural elucidation in solid and solution state and antimicrobial activity
作者： Saira Shahzadi , Saqib Ali , Klaus Wurst , Muhammad Najam-ul-Haq
DOI: 10.1002/HC.20380
关键词:
摘要: A series of organotin(IV) thiocarboxylates have been synthesized with the general formula R2SnL2 and R3SnL (R = Ph2(I), Me3(II), n-Bu3(III), Ph3(IV), Cy3(V), Me2(VI), n-Bu2(VII), L piperidine-1-thiocarboxylic acid) in anhydrous toluene under reflux conditions. The complexes were characterized by microanalysis, IR, 1H 13C NMR, mass spectrometry, XRD. NMR data revealed that thiocarboxylic acid acts as bidentate, exhibit four-coordinated geometry solution state. In solid state, diorganotin hexa-coordinated whereas triorganotin(IV) compounds show five-coordinated geometry. These also tested for their antimicrobial activity along ligand against different animals, plant pathogens, Artemia salina. All few exceptions high compared to ligand. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:664–674, 2007; Published online InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20380
sci-hub.se 参考文章(43)
Zbyszek Otwinowski, Wladek Minor, Processing of X-ray diffraction data collected in oscillation mode Methods in Enzymology. ,vol. 276, pp. 307- 326 ,(1997) , 10.1016/S0076-6879(97)76066-X
G. D. Thorn, R. A. Ludwig, The Dithiocarbamates and Related Compounds ,(1962)
Dimitri Coucouvanis, The Chemistry of the Dithioacid and 1,1-Dithiolate Complexes Progress in Inorganic Chemistry. pp. 233- 371 ,(2007) , 10.1002/9780470166123.CH4
G. Domazetis, R.J. Magee, B.D. James, Synthesis and structure of some triphenyltin(IV) dithiocarbamate compounds Journal of Organometallic Chemistry. ,vol. 141, pp. 57- 69 ,(1977) , 10.1016/S0022-328X(00)90667-3
Flavio Bonati, Renato Ugo, Organotin(IV) N,N-disubstituted dithiocarbamates Journal of Organometallic Chemistry. ,vol. 10, pp. 257- 268 ,(1967) , 10.1016/S0022-328X(00)93085-7
José Vicente, María Teresa Chicote, Sonia Huertas, Peter G. Jones, 1,1-ethylenedithiolato complexes of palladium(II) and platinum(II) with isocyanide and carbene ligands. Inorganic Chemistry. ,vol. 42, pp. 4268- 4274 ,(2003) , 10.1021/IC0343758
D.C. Menezes, F.T. Vieira, G.M. de Lima, A.O. Porto, M.E. Cortés, J.D. Ardisson, T.E. Albrecht-Schmitt, Tin(IV) complexes of pyrrolidinedithiocarbamate: synthesis, characterisation and antifungal activity. European Journal of Medicinal Chemistry. ,vol. 40, pp. 1277- 1282 ,(2005) , 10.1016/J.EJMECH.2005.07.008
Maochun Hong, Rong Cao, Hiroyuki Kawaguchi, Kazuyuki Tatsumi, Synthesis and Reactions of Group 6 Metal Half-Sandwich Complexes of 2,2-Dicyanoethylene-1,1-dichalcogenolates [(Cp*)M{E2CC(CN)2}2]- (M = Mo, W; E = S, Se) Inorganic Chemistry. ,vol. 41, pp. 4824- 4833 ,(2002) , 10.1021/IC025609A
D. Venkataraman, Geoffrey B. Gardner, Stephen Lee, Jeffrey S. Moore, Zeolite-like behavior of a coordination network Journal of the American Chemical Society. ,vol. 117, pp. 11600- 11601 ,(1995) , 10.1021/JA00151A034
TN Srivastava, Vijay Kumar, None, Some triorganotin(IV) Dithiocarbamates Journal of Organometallic Chemistry. ,vol. 107, pp. 55- 61 ,(1976) , 10.1016/S0022-328X(00)91774-1