[Mn2Ga4Sn4S20](8-) T3 supertetrahedral nanocluster directed by a series of transition metal complexes.
作者： Cheng-Yang Yue , Xiao-Wu Lei , Li-Juan Feng , Chen Wang , Ya-Ping Gong
DOI: 10.1039/C4DT02864C
关键词:
摘要: With different transition metal (TM) complexes as structure directing agents or building units, three new multinary chalcognidometalates based on T3 supertetrahedral nanocluster of [Mn2Ga4Sn4S20] 8− have been solvothermally synthesized and structurally characterized. In compound Mn2Ga4Sn4S20 [Mn2 (en) 5] 2· 4H2O (1, en= ethylenediamine), the neighboring [Mn2Ga4Sn4S20] 8− cores were bridged by two pairs of [Mn2 (en) 5] 4+ complex cations via Mn–S bonds to form one-dimensional (1D) neutral chains. Compound …
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