Catalytic reactivity of a meso-N-substituted corrole and evidence for a high-valent iron-oxo species.

作者: Amanda J. McGown , William D. Kerber , Hiroshi Fujii , David P. Goldberg

DOI: 10.1021/JA809183Z

关键词:

摘要: … a high-valent iron−oxo complex. We expected 1/H 2 O 2 would exhibit other catalytic activity typical of reactive high-valent iron… spectroscopic evidence for a high-valent iron−oxo corrole. …

参考文章(49)
W. T. Oosterhuis, G. Lang, Magnetic properties of the t2g4 configuration in low symmetry crystal fields The Journal of Chemical Physics. ,vol. 58, pp. 4757- 4765 ,(1973) , 10.1063/1.1679055
F. T. de Oliveira, A. Chanda, D. Banerjee, X. Shan, S. Mondal, L. Que, E. L. Bominaar, E. Munck, T. J. Collins, Chemical and Spectroscopic Evidence for an FeV-Oxo Complex Science. ,vol. 315, pp. 835- 838 ,(2007) , 10.1126/SCIENCE.1133417
Joseph P. Fox, Bobby Ramdhanie, Adelajda A. Zareba, Roman S. Czernuszewicz, David P. Goldberg, Copper(III) and vanadium(IV)-oxo corrolazines. Inorganic Chemistry. ,vol. 43, pp. 6600- 6608 ,(2004) , 10.1021/IC049384A
Hai-Yang Liu, Tat-Shing Lai, Lam-Lung Yeung, Chi K. Chang, First synthesis of perfluorinated corrole and its mn=o complex. Organic Letters. ,vol. 5, pp. 617- 620 ,(2003) , 10.1021/OL027111I
Atif Mahammed, Zeev Gross, Albumin-conjugated corrole metal complexes: extremely simple yet very efficient biomimetic oxidation systems. Journal of the American Chemical Society. ,vol. 127, pp. 2883- 2887 ,(2005) , 10.1021/JA045372C
Espen Tangen, Abhik Ghosh, Electronic Structure of High-Valent Transition Metal Corrolazine Complexes. The Young and Innocent? Journal of the American Chemical Society. ,vol. 124, pp. 8117- 8121 ,(2002) , 10.1021/JA0126935
Beaven S. Mandimutsira, Bobby Ramdhanie, Ryan C. Todd, Hailin Wang, Adelajda A. Zareba, Roman S. Czernuszewicz, David P. Goldberg, A stable manganese(V)-oxo corrolazine complex. Journal of the American Chemical Society. ,vol. 124, pp. 15170- 15171 ,(2002) , 10.1021/JA028651D