Use of infrared spectroscopy and density functional theory to study the influence of rubidium on alumina-supported molybdenum carbide catalyst for higher alcohol synthesis from syngas

作者: Heng Shou , Liwei Li , Daniela Ferrari , David S. Sholl , Robert J. Davis

DOI: 10.1016/J.JCAT.2012.12.011

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摘要: Molybdenum carbide nanoclusters supported on alumina were promoted by Rb 2 CO 3 and tested for higher alcohol synthesis from syngas. At 573K and 30bar syngas (H 2 /CO=1), the …

参考文章(81)
ALEX TULLO, HUNTSMAN READIES CORPORATE SPLIT Chemical & Engineering News. ,vol. 84, pp. 9- ,(2006) , 10.1021/CEN-V084N009.P009
P. Da Costa, C. Potvin, J.-M. Manoli, M. Breysse, G. Djéga-Mariadassou, Novel phosphorus-doped alumina-supported molybdenum and tungsten carbides: synthesis, characterization and hydrogenation properties Catalysis Letters. ,vol. 72, pp. 91- 97 ,(2001) , 10.1023/A:1009060526322
Bruce C. Gates, James R. Katzer, George C. A. Schuit, Chemistry of catalytic processes McGraw-Hill. ,(1979)
Takashi Aizawa, Shunichi Hishita, Takaho Tanaka, Shigeki Otani, Surface reconstruction of W2C(0001) Journal of Physics: Condensed Matter. ,vol. 23, pp. 305007- ,(2011) , 10.1088/0953-8984/23/30/305007
Hyun-Gyu Kim, Kyung Hee Lee, Jae Sung Lee, Carbon Monoxide Hydrogenation Over Molybdenum Carbide Catalysts Research on Chemical Intermediates. ,vol. 26, pp. 427- 443 ,(2000) , 10.1163/156856700X00435
Pio Forzatti, Enrico Tronconi, Italo Pasquon, Higher Alcohol Synthesis Catalysis Reviews-science and Engineering. ,vol. 33, pp. 109- 168 ,(1991) , 10.1080/01614949108020298
P. E. Blöchl, Projector augmented-wave method Physical Review B. ,vol. 50, pp. 17953- 17979 ,(1994) , 10.1103/PHYSREVB.50.17953
Enrique Iglesia, Fabio H. Ribeiro, Michel Boudart, Joseph E. Baumgartner, Tungsten carbides modified by chemisorbed oxygen. A new class of bifunctional catalysts Catalysis Today. ,vol. 15, pp. 455- 458 ,(1992) , 10.1016/0920-5861(92)85010-J