Pore structure of porous Mg-1Mn-xZn alloy fabricated by metal–gas eutectic unidirectional solidification

作者: Yanxiang Li , Yuan Liu , Huawei Zhang , Xiang Chen , Canxu Zhou

DOI: 10.1016/J.JMA.2021.03.026

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摘要: Abstract Lotus-type porous Mg–1 wt.% Mn–xZn (x = 0 wt.%, 1 wt.% and 2 wt.%) alloys were fabricated by metal–gas eutectic unidirectional solidification (the Gasar method). Effects of Zn addition the fabrication process on porosity, pore diameter microstructure Mg investigated. from 0 wt.% to 1 2 Mg–1 Mn alloy decreased porosity 41.2% 36.9% 35.8%, respectively, with same preparation processing. In lotus-type Mg–1 wt.%Mn–1 wt.%Zn alloy, porosities average diameters changed hydrogen pressures 0.1 0.6 MPa. Conical areas that rich in elemental existed below directional pores, precipitates also found conical areas. Homogeneous pores lower portion ingot, coarser finer non-directional formed upper part. A theoretical model change pressure agreed well calculated steady bubble growing area. The compressive strength Mg-1 wt.Mn-Zn can be increased around 20 MPa through rising Zinc content wt.%, which basically linearly decline increasing porosity. This work provides basis for Mg–Zn–Mn synthesis biological applications shows is a promising method fabricate controllable structure.

参考文章(28)
LI Yanxiang, Zhang Huawei, Liu Yuan, FABRICATION OF LOTUS-STRUCTURED POROUS MAGNESIUM WITH GASAR PROCESS Acta Metallurgica Sinica. ,vol. 40, pp. 1121- 1126 ,(2004)
Hua-Wei Zhang, Hydrogen Solubility in Pure Metals for Gasar Process Acta Metallurgica Sinica. ,vol. 43, pp. 113- 118 ,(2007)
P. Ghosh, M. Medraj, Thermodynamic calculation of the Mg-Mn-Zn and Mg-Mn-Ce systems and re-optimization of their constitutive binaries Calphad-computer Coupling of Phase Diagrams and Thermochemistry. ,vol. 41, pp. 89- 107 ,(2013) , 10.1016/J.CALPHAD.2013.01.008
X.N. Gu, W.R. Zhou, Y.F. Zheng, Y. Liu, Y.X. Li, Degradation and cytotoxicity of lotus-type porous pure magnesium as potential tissue engineering scaffold material Materials Letters. ,vol. 64, pp. 1871- 1874 ,(2010) , 10.1016/J.MATLET.2010.06.015
F. Rosalbino, S. De Negri, G. Scavino, A. Saccone, Microstructure and in vitro degradation performance of Mg-Zn-Mn alloys for biomedical application. Journal of Biomedical Materials Research Part A. ,vol. 101, pp. 704- 711 ,(2013) , 10.1002/JBM.A.34368
X. Sun, Z. Y. Cao, J. L. Zhang, D. M. Jiang, L. Guo, Mechanical and corrosion properties of newly developed Mg-Mn-Ca alloys as potential biodegradable implant materials Corrosion Engineering Science and Technology. ,vol. 49, pp. 303- 310 ,(2014) , 10.1179/1743278213Y.0000000146
Guang-rui JIANG, Yan-xiang LI, Yuan LIU, Calculation of hydrogen solubility in molten alloys Transactions of Nonferrous Metals Society of China. ,vol. 21, pp. 1130- 1135 ,(2011) , 10.1016/S1003-6326(11)60832-7
Liu Yuan, Li Yanxiang, A theoretical study of Gasarite eutectic growth Scripta Materialia. ,vol. 49, pp. 379- 386 ,(2003) , 10.1016/S1359-6462(03)00330-0
S.K Hyun, K Murakami, H Nakajima, Anisotropic mechanical properties of porous copper fabricated by unidirectional solidification Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 299, pp. 241- 248 ,(2001) , 10.1016/S0921-5093(00)01402-7
M. Jamesh, Satendra Kumar, T.S.N. Sankara Narayanan, Corrosion behavior of commercially pure Mg and ZM21 Mg alloy in Ringer’s solution – Long term evaluation by EIS Corrosion Science. ,vol. 53, pp. 645- 654 ,(2011) , 10.1016/J.CORSCI.2010.10.011