Preparation of well-defined colloidal barium titanate crystals by the controlled double-jet precipitation

作者: Y-S. Her , E. Matijevi , M.C. Chon

DOI: 10.1557/JMR.1995.3106

关键词:

摘要: A new method for the preparation of well-defined colloidal barium titanate (BaTiO3) crystals by controlled double-jet precipitation (CDJP) technique is described. The process extremely fast and requires a low temperature (<100 °C). reactants, titanium salts, can be used in high concentrations yield quantitative. stoichiometry BaTiO3 particles precisely reproducibly. effects composition reactant solutions, flow rates, reaction time, addition polymers on were investigated. powders, produced CDJP technique, sinter to density at as 1200 °C exhibit relative dielectric constant 5000 20 °C, which highest value reported literature. grain sizes sintered samples are small uniform, ranging between 1 2 μm.

参考文章(7)
A.L. Micheli, Synthesis of ceramic powders using an aqueous organic polymer precursor Ceramics International. ,vol. 15, pp. 131- 139 ,(1989) , 10.1016/0272-8842(89)90007-2
Tadao Sugimoto, Preparation of monodispersed colloidal particles Advances in Colloid and Interface Science. ,vol. 28, pp. 65- 108 ,(1987) , 10.1016/0001-8686(87)80009-X
Jiri Stavek, Milan Sipek, Izumi Hirasawa, Ken Toyokura, Controlled Double-Jet Precipitation of Sparingly Soluble Salts. A method for the Preparation of High Added Value Materials Chemistry of Materials. ,vol. 4, pp. 545- 555 ,(1992) , 10.1021/CM00021A012
Paola Gherardi, Egon Matijević, Homogeneous precipitation of spherical colloidal barium titanate particles Colloids and Surfaces. ,vol. 32, pp. 257- 274 ,(1988) , 10.1016/0166-6622(88)80021-0
Priya Bendale, Sridhar Venigalla, John R. Ambrose, Ellis D. Verink, James H. Adair, Preparation of Barium Titanate Films at 55oC by an Electrochemical Method Journal of the American Ceramic Society. ,vol. 76, pp. 2619- 2627 ,(1993) , 10.1111/J.1151-2916.1993.TB03990.X
Brian Pamplin, Preparation and properties of solid state materials Progress in Crystal Growth and Characterization. ,vol. 2, pp. 247- 248 ,(1979) , 10.1016/0146-3535(81)90035-6