Decomposition of nitrogen oxides on palladium and angle-resolved measurements of desorbing products
作者： Tatsuo Matsushima
关键词:
摘要: Recent angle-resolved measurements of desorbing products were reviewed for decomposition nitrogen oxides on noble metals. Two pathways the removal adsorbed atoms, i.e., N(a) + NO(a) → N2O(a) N2(g) O(a) and 2N(a) N2(g), examined typically Pd(110). The former takes place in presence gaseous CO shows two-directional N2 desorption collimated far from surface normal normally directed plane along [001] direction. latter does not contribute NO reaction model proposed inclined was also explained.
springer.com
sci-hub.se 参考文章(28)
Hideyuki Horino, Suwen Liu, Manami Sano, Sugio Wako, Atsuko Hiratsuka, Yuichi Ohno, Ivan Kobal, Tatsuo Matsushima, Ad-molecule orientation and thermo- and photo-induced surface-aligned desorption Topics in Catalysis. ,vol. 18, pp. 21- 26 ,(2002) , 10.1023/A:1013873931900
G.S. Herman, C.H.F. Peden, S.J. Schmieg, D.N. Belton, A comparison of the NO–CO reaction over Rh(100), Rh(110) and Rh(111) Catalysis Letters. ,vol. 62, pp. 131- 138 ,(1999) , 10.1023/A:1019090804419
Ivan Kobal, Kazushi Kimura, Yuichi Ohno, Hideyuki Horino, Izabela Rzeznicka, Tatsuo Matsushima, Nitrogen emission process in the decomposition of nitrogen oxides on Pd(110); an angular and velocity distribution study Studies in Surface Science and Catalysis. ,vol. 130, pp. 1337- 1342 ,(2000) , 10.1016/S0167-2991(00)80385-7
Y. Kim, J.A. Schreifels, J.M. White, Adsorption of N2O on Ru(001) Surface Science Letters. ,vol. 114, pp. 349- 361 ,(1982) , 10.1016/0039-6028(82)90476-9
B CHO, Mechanistic importance of intermediate N2O + CO reaction in overall NO + CO reaction system I. Kinetic analysis Journal of Catalysis. ,vol. 138, pp. 255- 266 ,(1992) , 10.1016/0021-9517(92)90021-9
H.H. Huang, C.S. Seet, Z. Zou, G.Q. Xu, The adsorption of N2O on clean and chemically modified Ru(001) surfaces Surface Science. ,vol. 356, pp. 181- 188 ,(1996) , 10.1016/0039-6028(96)00035-0
D.L Hildenbrand, K.H Lau, Dissociation energy of the PdO molecule Chemical Physics Letters. ,vol. 319, pp. 95- 98 ,(2000) , 10.1016/S0009-2614(00)00109-3
E J Heilweil, M P Casassa, R R Cavanagh, J C Stephenson, Picosecond Vibrational Energy Transfer Studies of Surface Adsorbates Annual Review of Physical Chemistry. ,vol. 40, pp. 143- 171 ,(1989) , 10.1146/ANNUREV.PC.40.100189.001043
P. Väterlein, T. Krause, M. Bäßler, R. Fink, E. Umbach, J. Taborski, V. Wüstenhagen, W. Wurth, Adsorption-induced bending of a triatomic molecule: Near-edge x-ray absorption fine-structure spectroscopy investigation of N2O adsorbed on different Ni(111) surfaces. Physical Review Letters. ,vol. 76, pp. 4749- 4752 ,(1996) , 10.1103/PHYSREVLETT.76.4749
D.E. Ibbotson, T.S. Wittrig, W.H. Weinberg, The chemisorption and decomposition of NO on the (110) surface of iridium Surface Science Letters. ,vol. 110, pp. 294- 312 ,(1981) , 10.1016/0039-6028(81)90640-3