Puckered-Boat Conformation Hexameric Water Clusters Stabilized in a 2D Metal−Organic Framework Structure Built from Cu(II) and 1,2,4,5-Benzenetetracarboxylic Acid
作者： Sujit K. Ghosh , Parimal K. Bharadwaj
DOI: 10.1021/IC049739Q
关键词:
摘要: 1,2,4,5-Benzenetetracarboxylic acid (btcH4) reacts with Cu(NO3)2·6H2O to form 2D coordination polymeric structure {[Cu2(btc)(Py)4·2H2O]·4H2O}n, 1, in the presence of pyridine from water at room temperature. Puckered-boat-shaped hexameric clusters resulting four free molecules and two coordinating metal ions join these sheets make a 3D network. These behave as pillars those which is key factor stabilizing Thermal analysis, X-ray powder diffraction, analysis have been used characterize this compound. Crystal data for 1 follow: triclinic space group P1, = 8.905(3) A, b 11.137(4) c 17.484(2) α 82.342(6)°, β 81.312(3)°, γ 82.361(4)° V= 1687.5(1)A3, Z 2, R1 0.0331, wR2 0.0886, S =1.066.
acs.org
unirioja.es
sci-hub.se 参考文章(31)
Leonard J. Barbour, G. William Orr, Jerry L. Atwood, An intermolecular (H2O)10 cluster in a solid-state supramolecular complex Nature. ,vol. 393, pp. 671- 673 ,(1998) , 10.1038/31441
Arindam Mukherjee, Manas K Saha, Munirathinam Nethaji, Akhil R Chakravarty, Arindam Mukherjee, Manas K Saha, Munirathinam Nethaji, Akhil R Chakravarty, Helical supramolecular host with aquapores anchoring alternate molecules of helical water chainsDedicated to Professor C. N. R. Rao on his 70th birthday.Electronic supplementary information (ESI) available: structural, spectral and magnetic data (Figs. S1-S5, Tables S1, S2). See http://www.rsc.org/suppdata/cc/b3/b316275c/ Chemical Communications. pp. 716- 717 ,(2004) , 10.1039/B316275C
F. N. Keutsch, R. J. Saykally, Water clusters: Untangling the mysteries of the liquid, one molecule at a time Proceedings of the National Academy of Sciences of the United States of America. ,vol. 98, pp. 10533- 10540 ,(2001) , 10.1073/PNAS.191266498
Lionel E. Cheruzel, Maxim S. Pometun, Matthew R. Cecil, Mark S. Mashuta, Richard J. Wittebort, Robert M. Buchanan, Structures and Solid-State Dynamics of One-Dimensional Water Chains Stabilized by Imidazole Channels Angewandte Chemie International Edition. ,vol. 42, pp. 5452- 5455 ,(2003) , 10.1002/ANIE.200352157
K. Liu, M. G. Brown, C. Carter, R. J. Saykally, J. K. Gregory, D. C. Clary, Characterization of a cage form of the water hexamer Nature. ,vol. 381, pp. 501- 503 ,(1996) , 10.1038/381501A0
Kyungsun Kim, Kenneth D. Jordan, Timothy S. Zwier, Low-Energy Structures and Vibrational Frequencies of the Water Hexamer: Comparison with Benzene-(H2O)6 Journal of the American Chemical Society. ,vol. 116, pp. 11568- 11569 ,(1994) , 10.1021/JA00104A047
K. Nauta, Formation of cyclic water hexamer in liquid helium: the smallest piece of Ice Science. ,vol. 287, pp. 293- 295 ,(2000) , 10.1126/SCIENCE.287.5451.293
Christopher J Gruenloh, Joel R Carney, Caleb A Arrington, Timothy S Zwier, Sharon Y Fredericks, Kenneth D Jordan, Infrared Spectrum of a Molecular Ice Cube: The S4 and D2d Water Octamers in Benzene-(Water)8 Science. ,vol. 276, pp. 1678- 1681 ,(1997) , 10.1126/SCIENCE.276.5319.1678
Yan-Ping Ren, La-Sheng Long, Bing-Wei Mao, You-Zhu Yuan, Rong-Bin Huang, Lan-Sun Zheng, Nanoporous Lanthanide–Copper(II) Coordination Polymers: Syntheses and Crystal Structures of [{M2(Cu3(iminodiacetate)6)}⋅8 H2O]n (M=La, Nd, Eu) Angewandte Chemie International Edition. ,vol. 42, pp. 532- 535 ,(2003) , 10.1002/ANIE.200390153
Adonis Michaelides, Stavroula Skoulika, Evangelos G. Bakalbassis, Jerzy Mrozinski, Cyclic Water Hexamers and Decamers in a Porous Lanthanide−Organic Framework: Correlation between Some Physical Properties and Crystal Structure Crystal Growth & Design. ,vol. 3, pp. 487- 492 ,(2003) , 10.1021/CG034025W