The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides
作者： Libor Čapek , Petr Kutálek , Lucie Smoláková , Martin Hájek , Ivana Troppová
DOI: 10.1007/S11244-013-0008-3
关键词:
摘要: The goal of this work is to study the effect thermal pre-treatment Mg/Al mixed oxides (450–1,050 °C) on their structure, basicity and catalytic activity in transesterification rapeseed oil. catalysts was shown depend not only amount basic sites, but also crystallite size MgO, specific surface area population medium/strong sites. Moreover, high stability Mg/Al-550 established by re-using catalyst four times. It associated with negligible magnesium leaching from solid liquid phases.
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Mayra G. Alvarez, Anna M. Segarra, Sandra Contreras, Jesús E. Sueiras, Francisco Medina, François Figueras, Enhanced use of renewable resources: Transesterification of glycerol catalyzed by hydrotalcite-like compounds Chemical Engineering Journal. ,vol. 161, pp. 340- 345 ,(2010) , 10.1016/J.CEJ.2009.12.036
Wenlei Xie, Haitao Li, Alumina-supported potassium iodide as a heterogeneous catalyst for biodiesel production from soybean oil Journal of Molecular Catalysis A: Chemical. ,vol. 255, pp. 1- 9 ,(2006) , 10.1016/J.MOLCATA.2006.03.061
V Díez, Effect of the chemical composition on the catalytic performance of MgyAlOx catalysts for alcohol elimination reactions Journal of Catalysis. ,vol. 215, pp. 220- 233 ,(2003) , 10.1016/S0021-9517(03)00010-1
Jianyi Shen, Mai Tu, Chen Hu, None, Structural and Surface Acid/Base Properties of Hydrotalcite-Derived MgAlO Oxides Calcined at Varying Temperatures Journal of Solid State Chemistry. ,vol. 137, pp. 295- 301 ,(1998) , 10.1006/JSSC.1997.7739
Kottapalli Koteswara Rao, Monique Gravelle, Jaime Sanchez Valente, François Figueras, Activation of Mg-Al hydrotalcite catalysts for aldol condensation reactions Journal of Catalysis. ,vol. 173, pp. 115- 121 ,(1998) , 10.1006/JCAT.1997.1878
Wenlei Xie, Hong Peng, Ligong Chen, Calcined Mg–Al hydrotalcites as solid base catalysts for methanolysis of soybean oil Journal of Molecular Catalysis A-chemical. ,vol. 246, pp. 24- 32 ,(2006) , 10.1016/J.MOLCATA.2005.10.008
A. Navajas, I. Campo, G. Arzamendi, W.Y. Hernández, L.F. Bobadilla, M.A. Centeno, J.A. Odriozola, L.M. Gandía, Synthesis of biodiesel from the methanolysis of sunflower oil using PURAL® Mg–Al hydrotalcites as catalyst precursors Applied Catalysis B-environmental. ,vol. 100, pp. 299- 309 ,(2010) , 10.1016/J.APCATB.2010.08.006
M.J. Climent, A. Corma, S. Iborra, J. Primo, Base Catalysis for Fine Chemicals Production: Claisen-Schmidt Condensation on Zeolites and Hydrotalcites for the Production of Chalcones and Flavanones of Pharmaceutical Interest Journal of Catalysis. ,vol. 151, pp. 60- 66 ,(1995) , 10.1006/JCAT.1995.1008
A. Brito, M. E. Borges, M. Garín, A. Hernández, Biodiesel Production from Waste Oil Using Mg−Al Layered Double Hydroxide Catalysts Energy & Fuels. ,vol. 23, pp. 2952- 2958 ,(2009) , 10.1021/EF801086P
Zhenqiang Yang, Wenlei Xie, Soybean oil transesterification over zinc oxide modified with alkali earth metals Fuel Processing Technology. ,vol. 88, pp. 631- 638 ,(2007) , 10.1016/J.FUPROC.2007.02.006