Experimental Simulation of Hydrate Accumulation and Dispersion in Pore Fluids

作者: Wanjun Lu , Feifei Wang , Menghan Wang , None

DOI: 10.1007/978-3-642-31101-7_8

关键词:

摘要: Dynamic accumulation and dispersion of gas hydrate in the stability zone are actually controlled by transformations methane between pore fluid. In this study, formation dissociation sediment column was simulated, experiment shows that can nucleate either at free gas-fluid interface or aqueous phase oversaturated with methane, both fine coarse sediments, but nucleates easier sediments. The processes dissolved from transported solution to precipitate surface crystal were monitored. Methane concentrations saline water equilibrium absence a vapor studied situ Raman spectroscopy. Hydrate growth dissolution induced temperature changes observed. rate is mass transportation solution.

参考文章(11)
H.C. Kim, P.R. Bishnoi, R.A. Heidemann, S.S.H. Rizvi, Kinetics of methane hydrate decomposition Chemical Engineering Science. ,vol. 42, pp. 1645- 1653 ,(1987) , 10.1016/0009-2509(87)80169-0
Zhenhao Duan, Nancy Møller, Jerry Greenberg, John H. Weare, The prediction of methane solubility in natural waters to high ionic strength from 0 to 250°C and from 0 to 1600 bar Geochimica et Cosmochimica Acta. ,vol. 56, pp. 1451- 1460 ,(1992) , 10.1016/0016-7037(92)90215-5
Phillip Servio, Peter Englezos, Measurement of Dissolved Methane in Water in Equilibrium with Its Hydrate Journal of Chemical & Engineering Data. ,vol. 47, pp. 87- 90 ,(2002) , 10.1021/JE0102255
M.K Davie, O.Y Zatsepina, B.A Buffett, Methane solubility in marine hydrate environments Marine Geology. ,vol. 203, pp. 177- 184 ,(2004) , 10.1016/S0025-3227(03)00331-1
Wenyue Xu, Carolyn Ruppel, Predicting the occurrence, distribution, and evolution of methane gas hydrate in porous marine sediments Journal of Geophysical Research: Solid Earth. ,vol. 104, pp. 5081- 5095 ,(1999) , 10.1029/1998JB900092
S.O. Yang, S.H. Cho, H. Lee, C.S. Lee, Measurement and prediction of phase equilibria for water + methane in hydrate forming conditions Fluid Phase Equilibria. ,vol. 185, pp. 53- 63 ,(2001) , 10.1016/S0378-3812(01)00456-3