Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
作者： Zoel Codolà , Laura Gómez , Scott T. Kleespies , Lawrence Que Jr , Miquel Costas
DOI: 10.1038/NCOMMS6865
关键词:
摘要: Non-haeme iron complexes are known to be competent catalysts for chemically driven water oxidation. Here, the authors provide evidence formation of an inner-sphere iron(IV)- oxygen-cerium(IV) intermediate that may mechanistic insight into naturally occurring oxygen evolving complex.
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