Synthesis and Characterisation of High Fullerene Content Polymers and Their Use in Organic Photovoltaic Devices
作者： Sean M. Clark , Jonathan A. Campbell , David A. Lewis
DOI: 10.1071/CH15284
关键词:
摘要: Narrow dispersity polymers with a high tethered fullerene content were synthesised by first polymerising poly(chloromethyl styrene) using reversible addition–fragmentation chain transfer (RAFT) polymerisation and subsequently functionalising them with pristine fullerene. The polymers comprised 52 % by weight fullerene, corresponding to approximately one fullerene per monomer in the polymer with a different morphology to poly(3-hexyl thiophene) (P3HT) : phenyl-C61-butyric acid methyl ester (PCBM) systems. Bulk heterojunctions formed from the polymer tethered fullerene (PTF) with P3HT yielded functioning organic photovoltaic devices with power conversion efficiencies ranging from 0.0030 to 0.22 % as the PTF was increased from 1 : 0.8 to 1 : 1.3. Process optimisation resulted in a maximum efficiency of 0.4 %.
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sci-hub.se 参考文章(23)
David Adam, The synthesis and characterisation of halogen and nitro phenyl azide derivatives as highly energetic materials Ludwig-Maximilians-Universität München. ,(2001)
John E Anthony, Antonio Facchetti, Martin Heeney, Seth R Marder, Xiaowei Zhan, n-Type organic semiconductors in organic electronics. Advanced Materials. ,vol. 22, pp. 3876- 3892 ,(2010) , 10.1002/ADMA.200903628
David J. Clarke, Janis G. Matisons, George P. Simon, Marek Samoc, Anna Samoc, Polyhedral oligomeric silsesquioxane-bound iminofullerene Applied Organometallic Chemistry. ,vol. 24, pp. 184- 188 ,(2010) , 10.1002/AOC.1568
Marleen H. van der Veen, Bert de Boer, Ulf Stalmach, Karin I. van de Wetering, Georges Hadziioannou, Donor-acceptor diblock copolymers based on PPV and C-60: Synthesis, thermal properties, and morphology Macromolecules. ,vol. 37, pp. 3673- 3684 ,(2004) , 10.1021/MA035643O
Henry. Ajie, Marcos M. Alvarez, Samir J. Anz, Rainer D. Beck, Francois. Diederich, K. Fostiropoulos, Donald R. Huffman, Wolfgang. Kraetschmer, Yves. Rubin, . et al., Characterization of the soluble all-carbon molecules C60 and C70 The Journal of Physical Chemistry. ,vol. 94, pp. 8630- 8633 ,(1990) , 10.1021/J100387A004
Mark Dante, Changduk Yang, Bright Walker, Fred Wudl, Thuc-Quyen Nguyen, Self‐Assembly and Charge‐Transport Properties of a Polythiophene–Fullerene Triblock Copolymer Advanced Materials. ,vol. 22, pp. 1835- 1839 ,(2010) , 10.1002/ADMA.200902696
Eugene. Lieber, C. N. R. Rao, T. S. Chao, C. W. W. Hoffman, Infrared Spectra of Organic Azides Analytical Chemistry. ,vol. 29, pp. 916- 918 ,(1957) , 10.1021/AC60126A016
R. Alex Marsh, Justin M. Hodgkiss, Sebastian Albert-Seifried, Richard H. Friend, Effect of Annealing on P3HT:PCBM Charge Transfer and Nanoscale Morphology Probed by Ultrafast Spectroscopy Nano Letters. ,vol. 10, pp. 923- 930 ,(2010) , 10.1021/NL9038289
Ulf Stalmach, Bert de Boer, Christine Videlot, Paul F. van Hutten, Georges Hadziioannou, Semiconducting Diblock Copolymers Synthesized by Means of Controlled Radical Polymerization Techniques Journal of the American Chemical Society. ,vol. 122, pp. 5464- 5472 ,(2000) , 10.1021/JA000160A
Francesco Giacalone, Nazario Martín, Fullerene polymers: synthesis and properties. Chemical Reviews. ,vol. 106, pp. 5136- 5190 ,(2006) , 10.1021/CR068389H