σ-Acceptor, Z-type ligands for transition metals
作者： Abderrahmane Amgoune , Didier Bourissou
DOI: 10.1039/C0CC04109B
关键词:
摘要: The ability of Lewis acids to coordinate transition metals as σ-acceptor ligands was recognized early in the 1970's, but so-called Z-type remained curiosities until 2000's. Over last decade, significant progress has been made this area, especially via incorporation acid moieties into multidentate, ambiphilic ligands. Our understanding nature and influence TM → Z interactions considerably improved scope susceptible behave significantly extended. This feature article summarizes these recent achievements.
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