N-Imidazolylation of Sulfoximines fromN-Cyano Sulfoximines, 1-Alkynes, andN-Sulfonyl Azides
作者： Sanghyuck Kim , Ji Eun Kim , Jinsub Lee , Phil Ho Lee
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摘要: The rhodium-catalyzed N-imidazolylation of N-sulfonyl-1,2,3-triazoles with a variety N-cyano sulfoximines has been developed for the synthesis N-imidazolyl via elimination molecular nitrogen. Copper-catalyzed [3+2] cycloaddition followed by from 1-alkynes, N-sulfonyl azides, and is also demonstrated in one-pot procedure.
sci-hub.se 参考文章(68)
Xiao Yun Chen, Long Wang, Marcus Frings, Carsten Bolm, Copper-catalyzed N-Alkynylations of sulfoximines with bromoacetylenes. Organic Letters. ,vol. 16, pp. 3796- 3799 ,(2014) , 10.1021/OL5016898
B Raguse, DD Ridley, The N-alkylation of sulfoximines Australian Journal of Chemistry. ,vol. 39, pp. 1655- 1659 ,(1986) , 10.1071/CH9861655
Tom van Dijk, Martijn S. Bakker, Flip Holtrop, Martin Nieger, J. Chris Slootweg, Koop Lammertsma, Base-stabilized nitrilium ions as convenient imine synthons. Organic Letters. ,vol. 17, pp. 1461- 1464 ,(2015) , 10.1021/ACS.ORGLETT.5B00339
Tomoya Miura, Tsuneaki Biyajima, Tetsuji Fujii, Masahiro Murakami, Synthesis of α-Amino Ketones from Terminal Alkynes via Rhodium-Catalyzed Denitrogenative Hydration of N-Sulfonyl-1,2,3-triazoles Journal of the American Chemical Society. ,vol. 134, pp. 194- 196 ,(2012) , 10.1021/JA2104203
Mitsuru Miyasaka, Koji Hirano, Tetsuya Satoh, Rafal Kowalczyk, Carsten Bolm, Masahiro Miura, Copper-catalyzed direct sulfoximination of azoles and polyfluoroarenes under ambient conditions. Organic Letters. ,vol. 13, pp. 359- 361 ,(2011) , 10.1021/OL102844Q
Daniel L. Priebbenow, Peter Becker, Carsten Bolm, Copper-catalyzed oxidative decarboxylative couplings of sulfoximines and aryl propiolic acids. Organic Letters. ,vol. 15, pp. 6155- 6157 ,(2013) , 10.1021/OL403106E
Cheol-Eui Kim, Sangjune Park, Dahan Eom, Boram Seo, Phil Ho Lee, Synthesis of pyrroles from terminal alkynes, N-sulfonyl azides, and alkenyl alkyl ethers through 1-sulfonyl-1,2,3-triazoles. Organic Letters. ,vol. 16, pp. 1900- 1903 ,(2014) , 10.1021/OL500718S
Seohyun Shin, Youngchul Park, Cheol-Eui Kim, Jeong-Yu Son, Phil Ho Lee, Synthesis of 2-Alkoxyaryl-2-aryl Enamines via Tandem Copper-Catalyzed Cycloaddition and Rhodium-Catalyzed Alkoxyarylation from Alkynes, N-Sulfonyl Azides, and Aryl Ethers Journal of Organic Chemistry. ,vol. 80, pp. 9803- 9803 ,(2015) , 10.1021/ACS.JOC.5B00891
Carsten Bolm, Jens P. Hildebrand, Jens Rudolph, Catalytic Coupling of Aryl Sulfonates with sp2-Hybridized Nitrogen Nucleophiles: Palladium- and Nickel-catalyzed Synthesis of N-Aryl Sulfoximines Synthesis. ,vol. 2000, pp. 911- 913 ,(2000) , 10.1055/S-2000-6287
Pazhamalai Anbarasan, Dongari Yadagiri, Shanmugam Rajasekar, Recent Advances in Transition-Metal-Catalyzed Denitrogenative Transformations of 1,2,3-Triazoles and Related Compounds Synthesis. ,vol. 46, pp. 3004- 3023 ,(2014) , 10.1055/S-0034-1379303