Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand
作者： Yasutomo Segawa , Makoto Yamashita , Kyoko Nozaki
DOI: 10.1021/JA9037092
关键词:
摘要: We synthesized a PBP pincer ligand precursor 2 and demonstrated its complexation with iridium(I) to afford the coordinatively unsaturated [PBP](hydrido)chloroiridium complex 3 via B−H oxidative addition. The reaction of carbon monoxide produced [PBP](hydrido)chloro(carbonyl)iridium 7. longer Ir−Cl bond length 7 than that 8 revealed stronger σ-donor ability PCP. Complex was also converted [PBP](ethylene)iridium(I) 9 by LiTMP under an ethylene atmosphere.
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