FUEL CELLS – MOLTEN CARBONATE FUEL CELLS | Anodes

作者: A. Hilmi , C. Yuh , M. Farooque

DOI: 10.1016/B978-044452745-5.00264-1

关键词:

摘要: High-temperature molten carbonate fuel cells are a highly efficient and environment-friendly source of power generation for commercial industrial customers. They operate efficiently at intermediate temperatures (550–650 °C) using variety light hydrocarbon fuels such as natural gas. Nickel alloyed with small amounts aluminium and/or chromium has been widely used the anode. The desired electrochemical performance, chemical stability creep strength porous anode have demonstrated in long-endurance stack operations (>30 000 h). Parameters affecting performance endurance well understood. alternating current-impedance analyses combination gain tests current interruption technique shown that is under mass-transfer control. In contrast to cathode, less sensitive cell temperature does not approach charge-transfer limitation even low (575 °C). An advanced design balanced pore structure developed suppress or reduce mass transfer enhance lifetime. materials currently useful life >5 years. Approaches manufacturing cost, improve develop low-cost alternative tolerance high-sulfur identified.

参考文章(25)
Y. Mugikura, Stack material and stack design Handbook of Fuel Cells. ,(2010) , 10.1002/9780470974001.F306076
Fumihiko Yoshiba, Hiroshi Morita, Masahiro Yoshikawa, Yoshihiro Mugikura, Yoshiyuki Izaki, Takao Watanabe, Mineo Komoda, Yuji Masuda, Nobuyuki Zaima, Improvement of electricity generating performance and life expectancy of MCFC stack by applying Li/Na carbonate electrolyte. Test results and analysis of 0.44 m 2 /10 kW- and 1.03 m 2 /10 kW-class stack Journal of Power Sources. ,vol. 128, pp. 152- 164 ,(2004) , 10.1016/J.JPOWSOUR.2003.10.011
C. Y. Yuh, J. R. Selman, The Polarization of Molten Carbonate Fuel Cell Electrodes II . Characterization by AC Impedance and Response to Current Interruption Journal of The Electrochemical Society. ,vol. 138, pp. 3649- 3656 ,(1991) , 10.1149/1.2085474
S. H. Lu, J. R. Selman, Kinetics of Hydrogen Oxidation in Molten Carbonate Application of Computer Curve‐Fitting Technique Journal of The Electrochemical Society. ,vol. 136, pp. 1068- 1074 ,(1989) , 10.1149/1.2096786
A. F. Sammells, S. B. Nicholson, P. G. P. Ang, Development of Sulfur‐Tolerant Components for the Molten Carbonate Fuel Cell Journal of The Electrochemical Society. ,vol. 127, pp. 350- 357 ,(1980) , 10.1149/1.2129669
C. Yuh, J. Colpetzer, K. Dickson, M. Farooque, G. Xu, Carbonate fuel cell materials Journal of Materials Engineering and Performance. ,vol. 15, pp. 457- 462 ,(2006) , 10.1361/105994906X117305
S. H. Lu, J. R. Selman, Electrode Kinetics of Fuel Oxidation at Copper in Molten Carbonate Journal of The Electrochemical Society. ,vol. 131, pp. 2827- 2833 ,(1984) , 10.1149/1.2115427
Leszek Suski, Agata Godula‐Jopek, J. Obła¸kowski, Wetting of Ni and NiO by Alternative Molten Carbonate Fuel Cell Electrolytes: I. Influence of Gas Atmosphere Journal of The Electrochemical Society. ,vol. 146, pp. 4048- 4054 ,(1999) , 10.1149/1.1392590