Multicyclic study on the carbonation of CaO using different limestones

作者: K. Chrissafis

DOI: 10.1007/S10973-006-7678-Z

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摘要: Different samples of limestones, with small differences in their stoichiometry, have been studied comparatively. The carbonation reaction has for a large area isothermal temperatures. conditions the multicyclic experiments calcination/carbonation were: temperature 670°C, heating time 60 min and carrier gas CO2. final conversion depends mainly on time. calcination percentage CaO that it not conversed to CaCO3 repeated experiments. quantity carbonated, same sample, affects values coefficients kinetic model fit reaction. In two four samples, was high enough comparison other calcite. At sample A reduction during first five cycles is less than at from literature. Under above experimental — specific consisted calcite can absorb larger quantities CO2 dolomite.

参考文章(30)
D Cazorla-Amoros, JP Joly, A Linares-Solano, A Marcilla-Gomis, C Salinas-Martinez de Lecea, None, Carbon dioxide-calcium oxide surface and bulk reactions: thermodynamic and kinetic approach The Journal of Physical Chemistry. ,vol. 95, pp. 6611- 6617 ,(1991) , 10.1021/J100170A043
T. Kaljuvee, A. Trikkel, R. Kuusik, Decarbonization of Natural Lime-containing Materials and Reactivity of Calcined Products Towards SO2 and CO2 Journal of Thermal Analysis and Calorimetry. ,vol. 64, pp. 1229- 1240 ,(2004) , 10.1023/A:1011561500091
J. Carlos Abanades, Diego Alvarez, Conversion Limits in the Reaction of CO2 with Lime Energy & Fuels. ,vol. 17, pp. 308- 315 ,(2003) , 10.1021/EF020152A
Shi-Ying Lin, Yoshizo Suzuki, Hiroyuki Hatano, Michiaki Harada, Developing an innovative method, HyPr-RING, to produce hydrogen from hydrocarbons Energy Conversion and Management. ,vol. 43, pp. 1283- 1290 ,(2002) , 10.1016/S0196-8904(02)00014-6
Yukitaka Kato, Daisuke Saku, Naozumi Harada, Yoshio Yoshizawa, UTILIZATION OF HIGH TEMPERATURE HEAT USING A CALCIUM OXIDE / LEAD OXIDE / CARBON DIOXIDE CHEMICAL HEAT PUMP Journal of Chemical Engineering of Japan. ,vol. 30, pp. 1013- 1019 ,(1997) , 10.1252/JCEJ.30.1013
Guangzhe Li, Toshihiro Kanie, Yukitaka Kato, Yoshio Yoshizawa, Heat and mass transfer in a packed bed reactor for calcium oxide/carbon dioxide chemical heat pump Journal of Chemical Engineering of Japan. ,vol. 35, pp. 886- 892 ,(2002) , 10.1252/JCEJ.35.886
A. SILABAN, M. NARCIDA, D. P. HARRISON, CHARACTERISTICS OF THE REVERSIBLE REACTION BETWEEN CO2(g) AND CALCINED DOLOMITE Chemical Engineering Communications. ,vol. 146, pp. 149- 162 ,(1996) , 10.1080/00986449608936487
A. SILABAN, D. P. HARRISON, HIGH TEMPERATURE CAPTURE OF CARBON DIOXIDE: CHARACTERISTICS OF THE REVERSIBLE REACTION BETWEEN CaO(s) and CO2(g) Chemical Engineering Communications. ,vol. 137, pp. 177- 190 ,(1995) , 10.1080/00986449508936375
T. Shimizu, T. Hirama, H. Hosoda, K. Kitano, M. Inagaki, K. Tejima, A twin fluid-bed reactor for removal of CO2 from combustion processes Chemical Engineering Research & Design. ,vol. 77, pp. 62- 68 ,(1999) , 10.1205/026387699525882
Ronald Barker, The reversibility of the reaction CaCO3 ⇄ CaO+CO2 Journal of Applied Chemistry and Biotechnology. ,vol. 23, pp. 733- 742 ,(2007) , 10.1002/JCTB.5020231005