Optimal current paths for model electrochemical systems

作者: Stanley J. Watowich , R. Stephen Berry

DOI: 10.1021/J100410A031

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摘要: Optimal control theory is used to determine process limits for a well-stirred fuel cell and diffusive flow cell, both operating with nonzero flows in finite time. Current paths optimal end states are determined cells constrained provide either maximum work output, effectiveness, or profit. A constant current path found optimize these three criteria of performance the cell. In qualitatively different, nonmonotonic trajectories obtained

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