Unusual metal complexes of N,N-bis(2-picolyl)amides – A comparative study of structure and reactivity
作者： Uwe Jakob , Thies Olaf Petersen , Willi Bannwarth
DOI: 10.1016/J.JORGANCHEM.2015.07.025
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摘要: Abstract Herein, we present hitherto unknown crystal structures of naphthalene-N,N-bis(2-picolyl)amide [NaphBPA] and its CuCl2-, CuBr2-, Cu(OTf)2-, ZnCl2-complexes. In each CuII-complex, obtained an unusual coordination mode which involves the amide nitrogen. This leads to a significant pyramidalization nitrogen causes higher methanolysis rate. contrast, ZnII is not coordinated by amidic pertinent [(NaphBPA)2Zn2Cl4]-complex does show remarkable reactivity.
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