A 119Sn NMR and Mössbauer study of some di- and tri-alkyltin(IV) alkoxides

作者: Peter J. Smith , R.F.M. White , Les Smith

DOI: 10.1016/S0022-328X(00)93372-2

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摘要: Abstract 119 Sn chemical shifts and 119m Mossbauer parameters of a series tributyltin alkoxides cyclic acyclic dibutyltin have been recorded, in order to study the self-association these molecules solid liquid states. The results show that degree association is markedly dependent upon size number alkoxide groups attached tin atom. Dilution temperature effects on are also described.

参考文章(32)
J.J. Zuckerman, Applications of119mSn Mössbauer Spectroscopy to the Study of Organotin Compounds Advances in Organometallic Chemistry. ,vol. 9, pp. 21- 134 ,(1971) , 10.1016/S0065-3055(08)60050-7
Rokuro Okawara, Masanori Wada, Structural Aspects of Organotin Compounds Advances in Organometallic Chemistry. ,vol. 5, pp. 137- 167 ,(1967) , 10.1016/S0065-3055(08)60091-X
Wm.J. Considine, Organotin chemistry Journal of Organometallic Chemistry. ,vol. 5, pp. 263- 266 ,(1966) , 10.1016/S0022-328X(00)80364-2
William J. Considine, Gerald A. Baum, Robert C. Jones, Organotin chemistry : VII. The NMR spectra of a distannoxane Journal of Organometallic Chemistry. ,vol. 3, pp. 308- 313 ,(1965) , 10.1016/S0022-328X(00)84650-1
R.C. Mehrotra, V.D. Gupta, Preparation and properties of some organotin compounds : I. Dibutyltin glycolates Journal of Organometallic Chemistry. ,vol. 4, pp. 145- 150 ,(1965) , 10.1016/S0022-328X(00)84379-X
R.C. Mehrotra, B.P. Bachlas, The reactions of dialkyltin diisopropoxides with 1-nitroso-2-naphthol Journal of Organometallic Chemistry. ,vol. 22, pp. 121- 128 ,(1970) , 10.1016/S0022-328X(00)83083-1
Curt Thies, Jack B. Kinsinger, Inorganic Condensation Reactions. I. Stannosiloxane Formation Inorganic Chemistry. ,vol. 3, pp. 551- 554 ,(1964) , 10.1021/IC50014A024
Kazuko Hayashi, Jun Iyoda, Isao Shiihara, Reaction of organotin oxides, alkoxides and acyloxides with organosilicon hydrides. New preparative method of organotin hydrides☆ Journal of Organometallic Chemistry. ,vol. 10, pp. 81- 94 ,(1967) , 10.1016/S0022-328X(00)81719-2
Shizuyoshi. Sakai, Yoji. Fujimura, Yoshio. Ishii, Reaction of hexaalkyl- and .alpha.,.alpha.'-dichlorotetraalkyldistannoxanes with cyclic carbonates Journal of Organic Chemistry. ,vol. 35, pp. 2344- 2347 ,(1970) , 10.1021/JO00832A052