Synthesis of Low-Density Heat-Resisting Polystyrene/Graphite Composite Microspheres Used as Water Carrying Fracturing Proppants

作者: Xiaobing Han , Qingxia Cheng , Feng Bao , Jie Gao , Yandan Yang

DOI: 10.1080/03602559.2014.919648

关键词:

摘要: Low-density heat resistamt, low-cost polystyrene (PS)/graphite microspheres were successfully synthesized via in situ suspension polymerization. Scanning electron microscopy (SEM) indicated that PS/graphite composite had good sphericity, and graphite particles evenly dispersed microspheres. Furthermore, density analysis illustrated the of composites was about 1.025–1.185 g/cm3 with suitability for carrying water. Thermodynamic testing revealed thermostability dramatically improved by introduction graphite, which is used deep underground. In addition, percentage damage decreased to 1.3% ratio 2.5% at 68 MPa. Therefore, PS/Graphite possess entirely feasible applications oil exploitation as pure water petroleum proppants.

参考文章(37)
L. Thomas McDaniel, Val G. Carithers, David R. Watson, Aluminosilicate ceramic proppant for gas and oil well fracturing and method of forming same ,(1983)
Philip D. Nguyen, Kirk Lynn Schreiner, Michael Dale Clark, Patrick L. Walker, Methods of preventing well fracture proppant flow-back ,(1997)
N. Mohan, S. Natarajan, S. P. Kumaresh Babu, Sliding Wear Behavior of Graphite Filled Glass-Epoxy Composites at Elevated Temperatures Polymer-plastics Technology and Engineering. ,vol. 50, pp. 251- 259 ,(2011) , 10.1080/03602559.2010.531606
Qiuju Qin, Yanni Zhong, Jiang Cheng, Shouping Xu, Xin Fan, Pihui Pi, Xiufang Wen, Preparation and characterization of porous titanium dioxide sulfonated polystyrene composite microspheres with amphiphilicity Journal of Applied Polymer Science. ,vol. 129, pp. 3482- 3489 ,(2013) , 10.1002/APP.39104
J. P. Pascault, R. J. J. Williams, Glass transition temperature versus conversion relationships for thermosetting polymers Journal of Polymer Science Part B: Polymer Physics. ,vol. 28, pp. 85- 95 ,(1990) , 10.1002/POLB.1990.090280107
Zaihang Zheng, Wenjie Li, Huimin Sun, Zhiqiang Cheng, Juntao Yan, Hongyan Wang, Xuejun Cui, Preparation and characterization of polystyrene/modified carbon black composite beads via in situ suspension polymerization Polymer Composites. ,vol. 34, pp. 1110- 1118 ,(2013) , 10.1002/PC.22519
Tao Wu, Kelong Huang, Suqin Liu, Shuxin Zhuang, Dong Fang, Sha Li, Dan Lu, Anqun Su, Hydrothermal ammoniated treatment of PAN-graphite felt for vanadium redox flow battery Journal of Solid State Electrochemistry. ,vol. 16, pp. 579- 585 ,(2012) , 10.1007/S10008-011-1383-Y
Abrahao T. Jardim Neto, Fernando Gaspar M. Prata, Julio Gomez, Carlos A. Pedroso, Marcio Martins, Dayana N. Silva, Ultralightweight Proppants: An Effective Approach To Address Problems in Long Horizontal Gravel Packs Offshore Brazil Spe Drilling & Completion. ,vol. 27, pp. 613- 624 ,(2012) , 10.2118/150581-PA
Jeong Hyun Yeum, Novel Poly(vinyl alcohol)/Clay Nanocomposite Microspheres via Suspension Polymerization and Saponification Polymer-plastics Technology and Engineering. ,vol. 50, pp. 1149- 1154 ,(2011) , 10.1080/03602559.2011.566302
Tiankui Guo, Shicheng Zhang, Lei Wang, Weibo Sui, Heng Wen, Optimization of proppant size for frac pack completion using a new equipment Journal of Petroleum Science and Engineering. ,vol. 96, pp. 1- 9 ,(2012) , 10.1016/J.PETROL.2012.08.007